The chemistry of heterocyclic carbenes has experienced a rapid development over the last
years. In addition to the imidazolin‐2‐ylidenes, a large number of cyclic diaminocarbenes …

Conspectus N-Heterocyclic carbenes (NHCs) are known to stabilize some metal atoms in
different oxidation states mostly by their strong σ-donation. After the successful syntheses of …

In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established
ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to …

The strong σ-donor but poor π-acceptor abilities of N-heterocyclic carbenes (NHCs) result in
chemical stability and coordination versatility, thus allowing them to coordinate with many …

Abstract Die Chemie der heterocyclischen Carbene hat sich in den letzten Jahren stürmisch
entwickelt. Nach den Imidazolin‐2‐ylidenen wurden weitere cyclische Diaminocarbene mit …

We report that the complex generated from Pd [P (o-tol) 3] 2 and the alkylbisphosphine CyPF-
t-Bu is a highly active and selective catalyst for the coupling of ammonia with aryl chlorides …

p K as of the conjugate acids of N-heterocyclic carbenes in water - Chemical Communications
(RSC Publishing) DOI:10.1039/C0CC03367G Royal Society of Chemistry View PDF …

Palladation of N3-alkylated 1, 2, 3-triazolium salts with Pd (OAc) 2 afforded a μ2− I2 bridged
bimetallic complex [Pd (trz) I2] 2 and monometallic bis (carbene) complexes Pd (trz) 2I2 as a …

A process for the preparation of symmetric and unsymmetric imidazolinium chlorides that
involves reaction of a formamidine with dichloroethane and a base (a) is described. This …

A series of four meta-phenylene-bridged bis-benzimidazolium chlorides were synthesized
as precursors to rigid, monoanionic, CCC-pincer N-heterocyclic carbene ligands. For …