In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

In 1967 Pederson reported the synthesis of macrocyclic crown ethers and their ability to
selectively bind alkali and alkaline earth ions, 1, 2 and since then supramolecular …

The effect of electron-withdrawing ligands on the energy barriers of Single-Molecule
Magnets (SMMs) is investigated. By introducing highly electron-withdrawing atoms on …

The binuclear complexes (3d–3d, 3d–3d′, 3d–4f) with compartmental ligands can
efficiently act as tectons in crystal engineering. Various high nuclearity clusters and …

The use of methylene-bridged calix [4] arenes in 3d/4f chemistry produces a family of
clusters of general formula [MnIII4LnIII4 (OH) 4 (C4) 4 (NO3) 2 (DMF) 6 (H2O) 6](OH) 2 …

We report the synthesis, crystal structures, and spectral, thermal, and magnetic properties of
a family of metal–organic perovskite ABX3,[C (NH2) 3][MII (HCOO) 3], in which A= C (NH2) 3 …

The synthesis, structure and magnetic properties of two isostructural heptametallic
lanthanide discs are reported, showing single molecule magnet (SMM) behaviour with a …

Polynuclear coordination clusters of 3d metals continue to attract the intense interest of
scientists from the synthetic inorganic chemistry, bioinorganic chemistry and molecular …

Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …

Single-molecule magnets (SMMs)[1–6] are chemically and physically interesting
compounds that exhibit hitherto unobserved magnetic properties. To prevent reversal of the …