IL Rusakova, YY Rusakov… - Russian Chemical Reviews, 2016 - iopscience.iop.org
The theoretical grounds of the modern relativistic methods for quantum chemical calculation of spin–spin coupling constants in nuclear magnetic resonance spectra are considered …
Einstein proposed his theory of special relativity in 1905. For a long time it was believed that this theory has no significant impact on chemistry. This view changed in the 1970s when it …
M Reiher, A Wolf - The Journal of chemical physics, 2004 - pubs.aip.org
Exact decoupling of positive-and negative-energy states in relativistic quantum chemistry is discussed in the framework of unitary transformation techniques. The obscure situation that …
The gravitational effects in the relativistic quantum mechanics are investigated. The exact Foldy-Wouthuysen transformation is constructed for the Dirac particle coupled to the static …
AJ Silenko - Physical Review A—Atomic, Molecular, and Optical …, 2008 - APS
A general method of the Foldy-Wouthyusen (FW) transformation for relativistic particles of arbitrary spin in strong external fields has been developed. The use of the found …
AJ Silenko - arXiv preprint math-ph/0404067, 2004 - arxiv.org
A method of Foldy-Wouthuysen transformation for relativistic spin-1/2 particles in external fields is proposed. It permits determination of the Hamilton operator in the Foldy …
In this paper, by using the canonical Foldy–Wouthuysen transformation for relativistic spin- 1/2 particles, we investigate the non-relativistic limit and determine the basic properties of …
Classical spin is described in terms of velocities and acceleration so that knowledge of advanced mathematics is not required. Written in the three-dimensional notation of vector …
VP Neznamov, AJ Silenko - Journal of mathematical physics, 2009 - pubs.aip.org
The block diagonalization of the Hamiltonian is not sufficient for the transformation to the Foldy–Wouthuysen (FW) representation. The conditions enabling the transition from the …