Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Despite growing progress in the construction of silazanes, the catalytic asymmetric synthesis
of silicon-stereogenic silazanes is significantly less explored and remains a considerable …

The N, N′-chelated conjugated bis-guanidinate (CBG) supported zinc hydride (Zn-1) pre-
catalyzed highly challenging chemoselective mono-hydrosilylation of a wide range of nitriles …

The involvement of planar carbocation intermediates is generally considered undesirable in
asymmetric catalysis due to the difficulty in gaining facial control and their intrinsic stability …

Organosilicon compounds play a crucial role as essential building blocks and valuable
organic molecules in various materials. They are extensively utilized as synthetic …

Alkyl boronic acids and their derivatives constitute vital building blocks in organic synthesis
and are important motifs identified in medicinal chemistry. Herein, we present a …

Group I alkoxides are highly active precatalysts in the heterodehydrocoupling of silanes and
amines to afford aminosilane products. The broadly soluble and commercially available …

An extended trisazo dipyridyl ligand, L, and its copper (I) complex,[1]+, were synthesized
and fully characterized. Complex [1]+ has five coordination geometry satisfied by ligand L. L …

Nitrenes are a highly reactive, yet fundamental compound class. They possess a mono-
valent nitrogen atom and usually a short life span, typically in the nanosecond range. Here …

In this study, we report on a CH functionalization of 1, 3-dicarbonyl compounds via a
photocatalytic nitrene transfer reaction. A wide range of 1, 3-dicarbonyl substrates and …