Luminescent radicals

A Mizuno, R Matsuoka, T Mibu, T Kusamoto - Chemical Reviews, 2024 - ACS Publications
Organic radicals are attracting increasing interest as a new class of molecular emitters. They
demonstrate electronic excitation and relaxation dynamics based on their doublet or higher …

Near-infrared luminescent open-shell π-conjugated systems with a bright lowest-energy zwitterionic singlet excited state

CP Yu, R Chowdhury, Y Fu, P Ghosh, W Zeng… - Science …, 2024 - science.org
Open-shell systems with extensive π-conjugation have fascinating properties due to their
narrow bandgaps and spin interactions. In this work, we report neutral open-shell di-and …

Spin-correlated luminescence of a carbazole-containing diradical emitter: single-molecule magnetoluminescence and thermally activated emission

A Mizuno, R Matsuoka, S Kimura, K Ochiai… - Journal of the …, 2024 - ACS Publications
Luminescent radicals have been intensively studied as a new class of materials exhibiting
novel photofunctions unique to open-shell systems. When luminescent radicals are …

Triple para-Functionalized Cations and Neutral Radicals of Enantiopure Diaza[4]helicenes

B Fabri, T Funaioli, L Frédéric, C Elsner… - Journal of the …, 2024 - ACS Publications
Modulation of absorbance and emission is key for the design of chiral chromophores.
Accessing a series of compounds absorbing and emitting (circularly polarized) light over a …

A Simple Molecular Design Strategy for Luminescent Radicals to Achieve Near-Infrared Emission

J Ding, M Zhang, Y Gao, C Lu… - The Journal of Physical …, 2023 - ACS Publications
The spin-allowed doublet emission of luminescent radicals has recently attracted significant
attention. However, the spectral range of most reported luminescent radical emitters and …

Stable Radical Polymers as New Electroactive Materials: Synthesis, Properties, and Emerging Applications

Y Xiong, Y Li, X Cui, S Li, X Peng, Y Ju… - Advanced Functional …, 2024 - Wiley Online Library
Extensive research over recent decades has demonstrated the feasibility of producing stable
radical polymers (SRPs) by exploring structure–stability relationships. Owing to their …

Dual Channel Emissions of Kasha and Anti‐Kasha from a Single Radical Molecule

Z Zhu, Z Kuang, L Shen, S Wang, X Ai… - Angewandte …, 2024 - Wiley Online Library
Stable open‐shell luminescent radicals have recently attracted much attention due to their
unique luminescence properties. However, a radical molecule with both Kasha and anti …

Steric Control of Luminescence in Phenyl-Substituted Trityl Radicals

P Murto, B Li, Y Fu, LE Walker, L Brown… - Journal of the …, 2024 - ACS Publications
Triphenylmethyl (trityl) radicals have shown potential for use in organic optoelectronic
applications, but the design of practical trityl structures has been limited to donor/radical …

Enhancing the Optically Detected Magnetic Resonance Signal of Organic Molecular Qubits

YR Poh, J Yuen-Zhou - ACS Central Science, 2025 - ACS Publications
In quantum information science and sensing, electron spins are often purified into a specific
polarization through an optical-spin interface, a process known as optically detected …

Radical Polymers for Simultaneous Singlet, Doublet, and Triplet Emission and Extended Spin Coherence Time

S Wang, Z Zhu, A Abdurahman, Q Peng - Macromolecules, 2024 - ACS Publications
Luminescent radical materials with multiple spin states hold immense potential for
applications in quantum information processing and spin optoelectronics, however research …