Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Despite of the many similarities between corroles and porphyrins, the chemistry of the former
remained undeveloped for decades because of severe synthetic obstacles. The recent …

An extremely simple biomimetic oxidation system, consisting of mixing metal complexes of
amphiphilic corroles with serum albumins, utilizes hydrogen peroxide for asymmetric …

Three series of cobalt (III) corroles were tested as catalysts for the electroreduction of
dioxygen to water. One was a simple monocorrole represented as (Me4Ph5Cor) Co, one a …

Transition metal complexes play a vital role as catalysts in organic syntheses, enhancing
selectivity and rates of many transformations. Typically iron is not the first choice when it …

Macrocyclic ligand chemistry is seen by a growing number of scientists as a tool for
designing new molecules with inherently selective properties. Metal coordinated …

Among metallocorroles, manganese corrole chemistry is one that has flourished prominently
in recent years. Numerous manganese corroles have been reported in which the oxidation …

The aim of this review is to highlight recent progress in the chemistry of corroles and core-
modified corroles. Emphasis is put on the synthetic and coordination aspects of corroles with …

High-valenttransition metal− oxo species are active oxidizing species in many metal-
catalyzed oxidation reactions in both Nature and the laboratory. In homogeneous catalytic …

New evidence concerning the mechanism of oxidation reactions of alkenes and aromatic
compounds catalyzed by metalloporphyrins with H2O2 were obtained based on the …