Molecular dynamics simulations of the electrical double layer on smectite surfaces contacting concentrated mixed electrolyte (NaCl–CaCl2) solutions

IC Bourg, G Sposito - Journal of colloid and interface science, 2011 - Elsevier
We report new molecular dynamics results elucidating the structure of the electrical double
layer (EDL) on smectite surfaces contacting mixed NaCl–CaCl 2 electrolyte solutions in the …

Anion exclusion effects in compacted bentonites: towards a better understanding of anion diffusion

LR Van Loon, MA Glaus, W Müller - Applied Geochemistry, 2007 - Elsevier
Diffusion of 36Cl− in compacted bentonite was studied using through-diffusion, out-diffusion
and profile analysis techniques. Both the bulk dry density of the bentonite and the …

Silicate weathering in anoxic marine sediments

K Wallmann, G Aloisi, M Haeckel, P Tishchenko… - … et Cosmochimica Acta, 2008 - Elsevier
Two sediment cores retrieved at the northern slope of Sakhalin Island, Sea of Okhotsk, were
analyzed for biogenic opal, organic carbon, carbonate, sulfur, major element concentrations …

Spectroscopic evidence for Fe (II)–Fe (III) electron transfer at clay mineral edge and basal sites

A Neumann, TL Olson, MM Scherer - Environmental science & …, 2013 - ACS Publications
Despite the importance of Fe redox cycling in clay minerals, the mechanism and location of
electron transfer remain unclear. More specifically, there is some controversy whether …

Electron transfer at the mineral/water interface: Selenium reduction by ferrous iron sorbed on clay

L Charlet, AC Scheinost, C Tournassat… - … et Cosmochimica Acta, 2007 - Elsevier
The mobility and availability of the toxic metalloid selenium in the environment are largely
controlled by sorption and redox reactions, which may proceed at temporal scales similar to …

Cation sorption on the muscovite (0 0 1) surface in chloride solutions using high-resolution X-ray reflectivity

ML Schlegel, KL Nagy, P Fenter, L Cheng… - … et Cosmochimica Acta, 2006 - Elsevier
The structure and mechanism of cation sorption at the (001) muscovite-water interface were
investigated in 0.01 and 0.5 m KCl, CsCl, and CaCl2 and 0.01 m BaCl2 solutions at slightly …

X-ray absorption and photoelectron spectroscopy investigation of selenite reduction by FeII-bearing minerals

AC Scheinost, R Kirsch, D Banerjee… - Journal of Contaminant …, 2008 - Elsevier
The long-lived radionuclide 79Se is one of the elements of concern for the safe storage of
high-level nuclear waste, since clay minerals in engineered barriers and natural aquifer …

A promising Zn-Ti layered double hydroxide/Fe-bearing montmorillonite composite as an efficient photocatalyst for Cr (VI) reduction: Insight into the role of Fe impurity …

C Chuaicham, Y Xiong, K Sekar, W Chen, L Zhang… - Applied Surface …, 2021 - Elsevier
Zn-Ti layered double hydroxide/montmorillonite (ZTL/MT) and Fe-doped ZTL/MT (ZTL/Fe@
MT20%) were prepared as photocatalyst for Cr (VI) reduction. The ZTL/Fe@ MT20 …

Effects of physical and geochemical heterogeneities on mineral transformation and biomass accumulation during biostimulation experiments at Rifle, Colorado

L Li, CI Steefel, MB Kowalsky, A Englert… - Journal of contaminant …, 2010 - Elsevier
Electron donor amendment for bioremediation often results in precipitation of secondary
minerals and the growth of biomass, both of which can potentially change flow paths and the …

Heterogeneous reduction of Tc (VII) by Fe (II) at the solid–water interface

T Peretyazhko, JM Zachara, SM Heald, BH Jeon… - … et Cosmochimica Acta, 2008 - Elsevier
Experiments were performed herein to investigate the rates and products of heterogeneous
reduction of Tc (VII) by Fe (II) adsorbed to hematite and goethite, and by Fe (II) associated …