Recent advances in separation-based techniques for synthetic polymer characterization

DM Meunier, JH Wade, M Janco, R Cong… - Analytical …, 2020 - ACS Publications
Structure dictates a polymeric material's properties and ultimately its performance in the
marketplace. Elucidation of structural differences among polymer samples is therefore …

Recent applications of the Successive Self-nucleation and Annealing thermal fractionation technique

RA Pérez-Camargo, D Cavallo, AJ Müller - Frontiers in Soft Matter, 2022 - frontiersin.org
Successive Self-nucleation and Annealing (SSA) is a thermal fractionation technique that is
performed by Differential Scanning Calorimetry (DSC). The combination of non-isothermal …

[HTML][HTML] 20 Years of polyolefin HPLC: Accomplishments and challenges

H Pasch, PE Bungu - European Polymer Journal, 2023 - Elsevier
The first publication on the interaction of polyolefins with stationary phases for high
performance liquid chromatography at high temperatures (HT-HPLC) appeared in 2003 …

Linking molecular structure to plant conditions: advanced analysis of a systematic set of mini-plant scale low density polyethylenes

KM Zentel, PSE Bungu, H Pasch, M Busch - Polymer Chemistry, 2021 - pubs.rsc.org
Two sample sets of low density polyethylene (LDPE) were investigated and differentiated via
comprehensive analysis of their microstructures with specific emphasis on branching. The …

Advances in High-Temperature Interaction Chromatography of Polyolefins: A Tutorial on Solvent and Temperature Gradient

PZ Ndlovu, A Lederer - Analytical Chemistry, 2024 - ACS Publications
The advancement of high-temperature interaction chromatography (HT-IC) is a key
milestone in polyolefin characterization. Temperature gradient interaction chromatography …

Stereochemical Heterogeneity Analysis of Polylactides by Multidimensional Liquid Chromatography

PS Eselem Bungu, K Luetzow, O Lettau… - Analytical …, 2024 - ACS Publications
A new and robust high-performance liquid chromatography (HPLC) method that separates
poly (lactic acid)(PLA) according to its stereochemical composition is presented. Using this …

Characterization of polyolefins

MI Malik, H Pasch - Molecular Characterization of Polymers, 2021 - Elsevier
Polyolefins constitute half of the annual polymer production worldwide. Polyolefins pose
special challenges for their analysis owing to their semicrystalline nature and insolubility in …

Comprehensive analysis of polyethylene graft copolymers by preparative fractionation, interaction chromatography, and thermal analysis

PS Eselem Bungu, K Zentel, S Hintenlang… - ACS Applied Polymer …, 2020 - ACS Publications
The comprehensive analysis of complex copolymers is a challenge and requires the
combination of results from different methods including size exclusion chromatography for …

[HTML][HTML] Low-Density Polyethylene–New insights into an old material under comparative studies using SEC-MALS, AF4-MALS, HT-HPLC and 2D-LC

JH Arndt, R Brüll, T Macko, S Deshmukh, M Monwar… - Polymer, 2024 - Elsevier
LDPE can be produced by different types of autoclave or tubular reactors, which can also be
cascaded. An important effort is to obtain materials with autoclave-process equivalent …

[PDF][PDF] Selectivity of thermal analysis in the branching analysis of low density polyethylene

PE Bungu, K Pflug, H Pasch - Macromol. Chem. Phys., 2020 - academia.edu
Low density polyethylene (LDPE) exhibits a complex branching architecture that is
characterized by the numbers and lengths of the branches. In previous work, it has been …