The analysis of the absolute configuration, enantiomeric composition, and concentration of
chiral compounds are frequently encountered tasks across the chemical and health …

This Perspective highlights the advances of optical methods for asymmetric reaction
discovery. Optical analysis allows for the determination of absolute configuration …

Axial chirality is a prevalent and important phenomenon in chemistry. Herein we report a
combination of dynamic covalent chemistry and axial chirality for the development of a …

Two achiral aromatic carboxylic acids that included the 1, 8-naphthalimide group and an
imidazolium cation were synthesized and exploited as chiroptical sensors. These …

This paper describes a simple method to determine the absolute configuration of amino
acids residues in peptides by mass spectrometry using a newly developed pair of mass …

Flexible biphenyls have been applied as efficient and practical chiroptical probes for
absolute configuration assignment to chiral primary amines. The mechanism of the central-to …

The use of stereodynamic probes is becoming one of the leading strategies for the fast and
effective determination of enantiomeric excess. Recently, we reported a series of novel …

A novel technique for the absolute stereochemical determination of alcohols has been
developed that uses crystallization of guanidinium salts of organosulfates. The simple one …

A method for determining the absolute configuration of β-chiral primary alcohols has been
developed. Enantioenriched alcohols were acylated in the presence of either enantiomer of …

Osmium tetroxide and TMEDA form stable crystalline adducts with alkenes. The structure of
liquid alkenes can be determined through the X-ray analysis of these derivatives. Osmium, a …