Cooperativity in noncovalent interactions

AS Mahadevi, GN Sastry - Chemical reviews, 2016 - ACS Publications
After conquering the atomic structure about a century ago, chemists have been largely
interested in understanding the concept of chemical bond and the formation of a molecule …

Molecular simulations of self-assembling bio-inspired supramolecular systems and their connection to experiments

PWJM Frederix, I Patmanidis, SJ Marrink - Chemical Society Reviews, 2018 - pubs.rsc.org
In bionanotechnology, the field of creating functional materials consisting of bio-inspired
molecules, the function and shape of a nanostructure only appear through the assembly of …

Into the dynamics of a supramolecular polymer at submolecular resolution

D Bochicchio, M Salvalaglio, GM Pavan - Nature Communications, 2017 - nature.com
To rationally design supramolecular polymers capable of self-healing or reconfiguring their
structure in a dynamically controlled way, it is imperative to gain access into the intrinsic …

Consequences of chirality on the dynamics of a water-soluble supramolecular polymer

MB Baker, L Albertazzi, IK Voets, CMA Leenders… - Nature …, 2015 - nature.com
The rational design of supramolecular polymers in water is imperative for their widespread
use, but the design principles for these systems are not well understood. Herein, we employ …

Dipole-moment-driven cooperative supramolecular polymerization

C Kulkarni, KK Bejagam, SP Senanayak… - Journal of the …, 2015 - ACS Publications
While the mechanism of self-assembly of π-conjugated molecules has been well studied to
gain control over the structure and functionality of supramolecular polymers, the …

Effect of H-bonding on order amplification in the growth of a supramolecular polymer in water

M Garzoni, MB Baker, CMA Leenders… - Journal of the …, 2016 - ACS Publications
While a great deal of knowledge on the roles of hydrogen bonding and hydrophobicity in
proteins has resulted in the creation of rationally designed and functional peptidic structures …

From cooperative self-assembly to water-soluble supramolecular polymers using coarse-grained simulations

D Bochicchio, GM Pavan - ACS nano, 2017 - ACS Publications
Supramolecular polymers, formed via noncovalent self-assembly of elementary monomers,
are extremely interesting for their dynamic bioinspired properties. In order to understand …

Molecular communications in complex systems of dynamic supramolecular polymers

M Crippa, C Perego, AL de Marco… - Nature Communications, 2022 - nature.com
Supramolecular polymers are composed of monomers that self-assemble non-covalently,
generating distributions of monodimensional fibres in continuous communication with each …

Low-Symmetry Self-Assembled Coordination Complexes with Exclusive Diastereoselectivity: Experimental and Computational Studies

SS Mishra, SVK Kompella, S Krishnaswamy… - Inorganic …, 2020 - ACS Publications
A pyridine/aniline appended unsymmetrical bidentate ligand N-(4-(4-aminobenzyl) phenyl)
nicotinamide, investigated in this work has two well-separated coordination sites …

Correlation between the selectivity and the structure of an asymmetric catalyst built on a chirally amplified supramolecular helical scaffold

A Desmarchelier, X Caumes, M Raynal… - Journal of the …, 2016 - ACS Publications
For the first time, supramolecular helical rods composed of an achiral metal complex and a
complementary enantiopure monomer provided a good level of enantioinduction in …