Biobased vitrimers: Towards sustainable and adaptable performing polymer materials

MA Lucherelli, A Duval, L Avérous - Progress in Polymer Science, 2022 - Elsevier
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …

Toward stimuli‐responsive dynamic thermosets through continuous development and improvements in covalent adaptable networks (CANs)

M Podgórski, BD Fairbanks, BE Kirkpatrick… - Advanced …, 2020 - Wiley Online Library
Covalent adaptable networks (CANs), unlike typical thermosets or other covalently
crosslinked networks, possess a unique, often dormant ability to activate one or more forms …

Elastic vitrimers: Beyond thermoplastic and thermoset elastomers

J Luo, Z Demchuk, X Zhao, T Saito, M Tian, AP Sokolov… - Matter, 2022 - cell.com
Thermoset elastomers are widely used in industry and frontier research due to their
advantage of mechanical robustness, high thermal/chemical resistance, and good …

Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities

ZP Zhang, MZ Rong, MQ Zhang - Progress in Polymer Science, 2018 - Elsevier
Reversible covalent polymers are able to change their bond arrangement and structure via
reversible reaction triggered by external stimuli including heating, light and pH, while …

Functional epoxy vitrimers and composites

Y Yang, Y Xu, Y Ji, Y Wei - Progress in Materials Science, 2021 - Elsevier
From cars to airplanes, from household appliances to indoor ornaments, from biomedical
devices to factory equipment, epoxy resins have been deeply rooted in modern society. But …

Recent development of repairable, malleable and recyclable thermosetting polymers through dynamic transesterification

T Liu, B Zhao, J Zhang - Polymer, 2020 - Elsevier
A fully polymerized (cured) thermoset is no longer capable of flow like a thermoplastic to be
recycled and reprocessed into a new object. Developing repairable, malleable and …

Vitrimers: permanent organic networks with glass-like fluidity

W Denissen, JM Winne, FE Du Prez - Chemical science, 2016 - pubs.rsc.org
Most covalent adaptable networks give highly interesting properties for material processing
such as reshaping, recycling and repairing. Classical thermally reversible chemical cross …

Malleable and recyclable thermosets: The next generation of plastics

Y Jin, Z Lei, P Taynton, S Huang, W Zhang - Matter, 2019 - cell.com
Malleable thermosets are crosslinked polymers containing dynamic covalent bonds, which
can be reversibly cleaved and reformed. They have attracted considerable attention in …

Epoxy resin with exchangeable disulfide crosslinks to obtain reprocessable, repairable and recyclable fiber-reinforced thermoset composites

AR de Luzuriaga, R Martin, N Markaide… - Materials …, 2016 - pubs.rsc.org
Fiber-reinforced polymer composites (FRPCs) made of a “dynamic” epoxy resin possess
good mechanical properties, while showing reprocessability, reparability and recyclability …

On the welding of vitrimers: Chemistry, mechanics and applications

Q Shi, C Jin, Z Chen, L An… - Advanced Functional …, 2023 - Wiley Online Library
Linear chains in thermoplastics make them relatively weak in performance but inherently
weldable and recyclable. By contrast, thermosets with permanently crosslinked networks …