Synthesis of Technetium Carboxylates: Wheel-Like Octanuclear Clusters (Tc8(μ-O)8(RCOO)16, Where R = CF3, C6H5)─Potential Nanobuilding Units for Tc …
MA Volkov, EV Abkhalimov, AP Novikov… - Inorganic …, 2024 - ACS Publications
Herein, we studied the behavior of TcO4–in trifluoroacetic anhydride (TFAA) under visible
light irradiation in situ by UV–vis spectroscopy. One carboxylate of Tc (VII) C2F3O5Tc (1) …
light irradiation in situ by UV–vis spectroscopy. One carboxylate of Tc (VII) C2F3O5Tc (1) …
Exploiting the Reactivity of Metal Trifluoroacetates to Access Alkali–Niobium (V) Oxyfluorides
Motivated by the lack of facile routes to alkali–niobium (V) oxyfluorides KNb2O5F and
CsNb2O5F, we investigated the reactivity of alkali trifluoroacetates KH (tfa) 2 and CsH (tfa) 2 …
CsNb2O5F, we investigated the reactivity of alkali trifluoroacetates KH (tfa) 2 and CsH (tfa) 2 …
HF-Free synthesis of colloidal Cs 2 ZrF 6 and (NH 4) 2 ZrF 6 nanocrystals
E Tzanetopoulos, J Schwartz… - Chemical Communications, 2023 - pubs.rsc.org
A solution-phase synthesis of colloidally stable A2BF6 nanocrystals is reported for the first
time, focusing on A+= Cs+, NH4+ and B4+= Zr4+. Handling hypertoxic HF is avoided by …
time, focusing on A+= Cs+, NH4+ and B4+= Zr4+. Handling hypertoxic HF is avoided by …
Series of new cobalt (II) and nickel (II) trinuclear fluorotrifluoroacetates with tetrahydrofuran–contribution to the inverse coordination chemistry and unique cations
ME Buzoverov, TY Glazunova… - Zeitschrift für …, 2023 - degruyter.com
The six new trinuclear fluorocarboxylates with tetrahydrofuran (THF) molecules as terminal
ligands are presented. The structures of compounds have been determined by single-crystal …
ligands are presented. The structures of compounds have been determined by single-crystal …