Hypervalent iodine reagents in the total synthesis of natural products

LF Silva Jr, B Olofsson - Natural product reports, 2011 - pubs.rsc.org
Covering: 2008–2010 This report describes the recent applications of hypervalent iodine
reagents in the total synthesis of natural products. The large diversity of high-yielding and …

Recent applications of the Suzuki reaction in total synthesis

MM Heravi, E Hashemi - Tetrahedron, 2012 - Elsevier
Conclusions The structural diversity of the natural product targets described in this review
illustrates the versatility of Suzuki–Miyaura cross coupling reactions. The reactions tolerated …

Perspectives from nearly five decades of total synthesis of natural products and their analogues for biology and medicine

KC Nicolaou, S Rigol - Natural product reports, 2020 - pubs.rsc.org
Covering: 1970 to 2020 By definition total synthesis is the art and science of making the
molecules of living Nature in the laboratory, and by extension, their analogues. Although …

Achmatowicz reaction and its application in the syntheses of bioactive molecules

AK Ghosh, M Brindisi - RSC advances, 2016 - pubs.rsc.org
Substituted pyranones and tetrahydropyrans are structural subunits of many bioactive
natural products. Considerable effort is devoted toward the chemical synthesis of these …

Selective deprotection of silyl ethers

RD Crouch - Tetrahedron, 2013 - Elsevier
Reactions, which permit the selective deprotection of one silyl-protected alcohol in the
presence of another are reviewed. This review covers examples reported in the literature …

Transition metal-catalysed cross-coupling reactions of P-activated enols

JD Sellars, PG Steel - Chemical Society Reviews, 2011 - pubs.rsc.org
Transition metal catalysed cross-coupling reactions are ubiquitous in organic chemistry
providing an impressive technique for C–C bond formation. Whilst many electrophilic …

Enzymatic aerobic ring rearrangement of optically active furylcarbinols

D Thiel, D Doknić, J Deska - Nature Communications, 2014 - nature.com
Biogenic furans are currently discussed as highly attractive alternative feedstock in a post-
fossil society; thus, also the creation of sustainable furan valorization pathways appears of …

Total synthesis endeavors and their contributions to science and society: A personal account

KC Nicolaou, S Rigol, R Yu - CCS Chemistry, 2019 - chinesechemsoc.org
The advent of organic synthesis in the 19th century, serendipitous as it was, set in motion a
revolution in science that continues to evolve into increasing levels of sophistication and to …

Manganese-Catalyzed Achmatowicz Rearrangement Using Green Oxidant H2O2

Q Xing, Z Hao, J Hou, G Li, Z Gao, J Gou… - The Journal of Organic …, 2021 - ACS Publications
Oxidation reactions have been extensively studied in the context of the transformations of
biomass-derived furans. However, in contrast to the vast literature on utilizing the …

Recent applications of the Horner-Wadsworth-Emmons reaction to the synthesis of natural products

A Bisceglia, LR Orelli - Current Organic Chemistry, 2012 - ingentaconnect.com
The Horner-Wadsworth-Emmons reaction has evolved in the last years as one of the most
powerful and reliable method for stereocontrolled olefin synthesis. The reaction has become …