Organic compounds labeled with hydrogen isotopes play a crucial role in numerous areas,
from materials science to medicinal chemistry. Indeed, while the replacement of hydrogen by …

In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Rearrangement reactions, one of the most significant transformations in organic chemistry,
play an irreplaceable role in improving synthetic efficiency and molecular complexity …

Deuterated chemicals are becoming irreplaceable in pharmaceutical engineering, material
science and synthetic chemistry. Many excellent reviews have discussed acid/base …

Glycosyl radical functionalization is one of the central topics in synthetic carbohydrate
chemistry. Recent advances in metal‐catalyzed cross‐coupling chemistry and …

A Pd (0)/blue light catalyzed carboiodination reaction is reported. A simple, air-stable
catalytic system, utilizing [Pd (allyl) Cl] 2 and DPEPhos, generated a variety of iodinated …

The first deoxygenative Heck reactions are described, as illustrated by formate-mediated
cine-substitutions of vinyl triflates with aryl iodides. The collective data corroborate a …

Visible light‐induced Pd catalysis has emerged as a promising subfield of photocatalysis.
The hybrid nature of Pd radical species has enabled a wide array of radical‐based …

Excited-state palladium catalysis has emerged as a promising strategy for developing novel
and valuable reactions. Herein, we report the first excited-state Pd-catalyzed 1, 2-radical …

Photoredox catalysis has recently emerged as a powerful synthetic platform for accessing
complex chemical structures through non-traditional bond disconnection strategies that …