Thermal disorder prevents the suppression of ultra-fast photochemistry in the strong light-matter coupling regime

A Dutta, V Tiainen, I Sokolovskii, L Duarte… - Nature …, 2024 - nature.com
Strong coupling between molecules and confined light modes of optical cavities to form
polaritons can alter photochemistry, but the origin of this effect remains largely unknown …

Multi-scale molecular dynamics simulations of enhanced energy transfer in organic molecules under strong coupling

I Sokolovskii, RH Tichauer, D Morozov, J Feist… - Nature …, 2023 - nature.com
Exciton transport can be enhanced in the strong coupling regime where excitons hybridize
with confined light modes to form polaritons. Because polaritons have group velocity, their …

Polariton localization and dispersion properties of disordered quantum emitters in multimode microcavities

G Engelhardt, J Cao - Physical review letters, 2023 - APS
Experiments have demonstrated that the strong light-matter coupling in polaritonic
microcavities significantly enhances transport. Motivated by these experiments, we have …

Theoretical analysis of exciton wave packet dynamics in polaritonic wires

GJR Aroeira, KT Kairys, RF Ribeiro - The Journal of Physical …, 2023 - ACS Publications
We present a comprehensive study of the exciton wave packet evolution in disordered
lossless polaritonic wires. Our simulations reveal signatures of ballistic, diffusive, and …

Tuning the Coherent Propagation of Organic Exciton‐Polaritons through the Cavity Q‐factor

RH Tichauer, I Sokolovskii, G Groenhof - Advanced Science, 2023 - Wiley Online Library
Transport of excitons in organic materials can be enhanced through polariton formation
when the interaction strength between these excitons and the confined light modes of an …

Coherent transient exciton transport in disordered polaritonic wires

GJR Aroeira, KT Kairys, RF Ribeiro - Nanophotonics, 2024 - degruyter.com
Excitation energy transport can be significantly enhanced by strong light–matter interactions.
In the present work, we explore intriguing features of coherent transient exciton wave packet …

Extracting accurate light–matter couplings from disordered polaritons

K Schwennicke, NC Giebink, J Yuen-Zhou - Nanophotonics, 2024 - degruyter.com
The vacuum Rabi splitting (VRS) in molecular polaritons stands as a fundamental measure
of collective light–matter coupling. Despite its significance, the impact of molecular disorder …

Vibrational polariton transport in disordered media

E Suyabatmaz, RF Ribeiro - The Journal of Chemical Physics, 2023 - pubs.aip.org
Chemical reactions and energy transport phenomena have been experimentally reported to
be significantly affected by strong light–matter interactions and vibrational polariton …

Kubo-Anderson theory of polariton line shape

C Climent, JE Subotnik, A Nitzan - Physical Review A, 2024 - APS
We apply the Kubo-Anderson stochastic theory of molecular spectral line shapes to the case
of polaritons formed in the collective strong-coupling regime. We investigate both the fast …

[PDF][PDF] Frequency-dependent photoreactivity in disordered molecular polaritons

JB Pérez-Sánchez, F Mellini, NC Giebink… - arXiv preprint arXiv …, 2023 - researchgate.net
We present a powerful formalism (d-CUT-E) to simulate the ultrafast quantum dynamics of
molecular polaritons in the collective strong coupling regime, where a disordered ensemble …