Monofluorination of organic compounds: 10 years of innovation

PA Champagne, J Desroches, JD Hamel… - Chemical …, 2015 - ACS Publications
Taking into account the vast arrays of fluorinated motifs known, 11 this review will be limited
to the monofluorination of organic compounds, ie, synthetic methods allowing the …

Organofluorine chemistry: Promising growth areas and challenges

LV Politanskaya, GA Selivanova… - Russian Chemical …, 2019 - iopscience.iop.org
Currently, the chemistry of organofluorine compounds is a leading and rapidly developing
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

A review on DBU-mediated organic transformations

SK Boddu, N Ur Rehman, TK Mohanta… - … Chemistry Letters and …, 2022 - Taylor & Francis
Diazabicyclo [5.4. 0] undec-7-ene (DBU) has received a significant importance in organic
synthesis during recent years because of its interesting ability to catalyze organic reaction …

Radical Nitration-Debromination of α-Bromo-α-fluoroalkenes as a Stereoselective Route to Aromatic α-Fluoronitroalkenes Functionalized Fluorinated Building …

VA Motornov, VM Muzalevskiy, AA Tabolin… - The Journal of …, 2017 - ACS Publications
A new highly efficient method for the synthesis of 2-fluoro-2-nitrostyrenes was described.
Radical nitration of readily available 2-bromo-2-fluorostyrenes with Fe (NO3) 3· 9H2O …

Copper‐Catalyzed α‐Arylation of Nitroalkanes with (Hetero) aryl Bromides/Iodides

J Huang, T Li, X Lu, D Ma - Angewandte Chemie, 2024 - Wiley Online Library
Abstract α‐Aryl substituted nitroalkanes are valuable synthetic building blocks that can be
easily converted into α‐aryl substituted aldehydes, ketones, carboxylic acids, as well as …

1, 8-Diazabicyclo [5.4. 0] undec-7-ene (DBU): A versatile reagent in organic synthesis

B Nand, G Khanna, A Chaudhary, A Lumb… - Current organic …, 2015 - benthamdirect.com
This review focuses on the catalytic activity of the organic bicyclic amidine base, 1, 8-
diazabicyclo [5.4. 0] undec-7-ene (DBU). It is available commercially, cheap and a …

Organocatalytic insertion of isatins into aryl difluoronitromethyl ketones

R Ding, PR Bakhshi, C Wolf - The Journal of organic chemistry, 2017 - ACS Publications
An organocatalytic method that achieves insertion of isatins into aryl difluoronitromethyl
ketones under mild conditions is described. The reaction occurs in the presence of 20 mol …

Catalytic insertion of aldehydes into dihalonitroacetophenones via sequential bond scission-aldol reaction-acyl transfer

R Ding, C Wolf - Chemical Communications, 2016 - pubs.rsc.org
A catalytic process that provides dihalogenated nitro alcohols in up to 99% yield and with
100% atom economy is described. In situ cleavage of dihalonitroacetophenones affords …

α-Fluorination of β-ketosulfones by Selectfluor™ F–TEDA–BF4

H Loghmani-Khouzani, MR Poorheravi, MMM Sadeghi… - Tetrahedron, 2008 - Elsevier
Attempted fluorination of β-ketosulfides using Selectfluor™ resulted only in the isolation of
the corresponding diaryl disulfides, presumed to arise by decomposition of an unstable …

Diethyl fluoronitromethylphosphonate: Synthesis and application in nucleophilic fluoroalkyl additions

S Opekar, R Pohl, P Beran, L Rulíšek… - Chemistry–A European …, 2014 - Wiley Online Library
Abstract Diethyl fluoronitromethylphosphonate (3), a previously unknown compound, was
synthesized by electrophilic fluorination of diethyl nitromethylphosphonate with Selectfluor …