The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

Over the past three decades, the field of coordination polymers (CPs) and metal–organic
frameworks (MOFs) has developed rapidly due to the potential applications of these …

Modern energy challenges have amplified interest in transition metal-based molecular
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …

The use of first row transition metal complexes is one of the mainstreams in modern
homogeneous catalysis. The case of manganese is peculiar in that catalytic applications of …

The electrocatalytic activity for CO2 reduction is greatly enhanced for Co complexes with
pyridyldiimine-based ligands through the stepwise integration of three synergistic …

One approach for the conversion of CO 2 into fuels or fuel precursors is the proton-coupled
reduction of CO 2 to CO or formic acid, using transition metal complexes as catalysts in …

In situ surface-enhanced spectroscopic and reactivity investigations of the electrochemical
reduction of CO2 at low overpotentials (< 0.7 V) was conducted on Cu surfaces. Vibrational …

The traditional synthesis of syngas, a mixture of CO and H 2, relies on the reverse water gas
shift reaction at high temperature and thus consumes considerable energy and resources. In …

We report here the first purely organometallic fac‐[MnI (CO) 3 (bis‐MeNHC) Br] complex with
unprecedented activity for the selective electrocatalytic reduction of CO2 to CO, exceeding …