Steering On-Surface Reactions by Kinetic and Thermodynamic Strategies

T Wang, Q Fan, J Zhu - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
On-surface synthesis has emerged as a powerful tool to fabricate various functional low-
dimensional nanostructures with atomic precision, thus becoming a promising platform for …

Tuning the diradical character of pentacene derivatives via non-benzenoid coupling motifs

T Wang, P Angulo-Portugal… - Journal of the …, 2023 - ACS Publications
The development of functional organic molecules requires structures of increasing size and
complexity, which are typically obtained by the covalent coupling of smaller building blocks …

Dramatic acceleration of the Hopf cyclization on gold (111): From enediynes to peri-fused diindenochrysene graphene nanoribbons

C Zhao, DD Bhagwandin, W Xu… - Journal of the …, 2024 - ACS Publications
Hopf et al. reported the high-temperature 6π-electrocyclization of cis-hexa-1, 3-diene-5-yne
to benzene in 1969. Subsequent studies using this cyclization have been limited by its very …

On-surface synthesis of 2D porphyrin-based covalent organic frameworks using terminal alkynes

S Chen, H Wang, Z Ou, H Liu, J Zhou, P Hu… - Chemistry of …, 2021 - ACS Publications
The surface chemistry of large molecules such as tetraphenylporphyrin molecules
functionalized with terminal alkyne groups has not yet been studied, as these molecules are …

Challenges in the synthesis of corannulene-based non-planar nanographenes on Au (111) surfaces

T Wang, J Lawrence, N Sumi, R Robles… - Physical Chemistry …, 2021 - pubs.rsc.org
The on-surface synthesis of non-planar nanographenes is a challenging task. Herein, with
the aid of bond-resolving scanning tunneling microscopy (BRSTM) and density functional …