Supramolecular functional materials represent an emerging class of materials that have
been governed by the supramolecular chemistry of self-assembled molecules. Such high …

Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …

The interactions between SbF6–and metal nanoclusters are of significance for customizing
clusters from both structure and property aspects; however, the whole-segment monitoring of …

Herein, a series of face-capped (Tr2M3) 4L4 (Tr= cycloheptatrienyl cationic ring; M= metal;
L= organosulfur ligand) tetrahedral cages 1–3 functionalized with 12 appended crown ether …

The use of copper (I) in metal–organic assemblies leads readily to the formation of simple
grids and helicates, whereas higher-order structures require complex ligand designs. Here …

The emerging metal nanocluster provides a platform for the investigation of structural
features, unique properties, and structure–property correlation of nanomaterials at the …

Luminescent metal–organic cages are of great interest in contemporary research; however,
their designed synthesis remains challenging. Here, we created metal-cluster-derived …

Tangled cubes feature the topology of typical Platonic cubes, with their “faces” traversed by
edges in different ways. This study generates an “A‐type” tangled metallocube from the …

Due to the ubiquity of chirality in nature, chiral self‐assembly involving self‐sorting
behaviors has remained as one of the most important research topics of interests. Herein …

Stimuli-responsive structural transformation has attracted much attention for its potential to
mimic the behavior of biological transformations and functions. Here, two unprecedented …