Recent advances of one-dimensional coordination polymers as catalysts

E Loukopoulos, GE Kostakis - Journal of Coordination Chemistry, 2018 - Taylor & Francis
This review aims to provide reports of one dimensional (1-D) coordination polymers that
have been used as catalysts in various organic reactions in the last decade, covering the …

Incorporating heterogeneous lacunary Keggin anions as efficient catalysts for solvent-free cyanosilylation of aldehydes and ketones

M Malmir, MM Heravi, Z Yekke-Ghasemi, M Mirzaei - Scientific Reports, 2022 - nature.com
Polyoxometalates (POMs) as efficient catalysts can be used a wide range of chemical
transformations due to their tunable Brønsted/Lewis-acidity and redox properties. Herein, we …

Classical and interdisciplinary approaches to the design of organic and hybrid molecular systems

AN Vereshchagin - Russian Chemical Bulletin, 2017 - Springer
This review summarizes the recent advances in the construction of organic and hybrid
systems having considerable potential for practical applications in pharmacology, medicine …

Half-Sandwich Ruthenium Complexes with Hydrazone Ligands: Preparation, Structure, and Catalytic Activity in Cyanosilylether Synthesis under an Air Atmosphere

K Wang, H Li, L Yang, ZJ Liu, ZJ Yao - Inorganic Chemistry, 2023 - ACS Publications
A new class of N, O-coordinate half-sandwich ruthenium complexes supported by
hydrazone ligands with a general formula of [Ru (η6-p-cymene) Cl (L)] have been obtained …

[HTML][HTML] Monosubstituted Keggin as heterogeneous catalysts for solvent-free cyanosilylation of aldehydes and ketones

Z Yekke-Ghasemi, MM Heravi, M Malmir… - Catalysis …, 2022 - Elsevier
Any successful catalyst should have a dedicated synthesizing route considering their high
yields, time-efficient, and do not require any highly toxic chemicals. In this regard, two nano …

Waste-Minimized Cyanosilylation of Carbonyls Using Fluoride on Polymeric Ionic Tags in Batch and under Continuous Flow Conditions

F Ferlin, F Valentini, G Brufani, D Lanari… - ACS Sustainable …, 2021 - ACS Publications
Herein, we report the development of a tailor-made fluoride-based heterogeneous catalyst,
POLITAG-F, for the waste-minimized continuous production of cyanohydrin silyl ethers. The …

Theoretical Insights into Aluminum-Catalyzed Cyanosilylation of Aldehydes and Ketones

S De, S Dutta, D Koley - Organometallics, 2022 - ACS Publications
Since main-group catalysts are more advantageous than transition metal catalysts from both
economic and environmental viewpoints, their development and utilization, especially group …

Two polyoxoniobates-based ionic crystals as Lewis base catalysts for cyanosilylation

S Li, P Ji, S Han, Z Hao, X Chen - Inorganic Chemistry Communications, 2020 - Elsevier
Two transition-metal containing heteropolyniobates, H [Ni (en) 3] 5 [VNb 12 O 40 (VO) 2]·
15H 2 O (1) and H 3 [Cu (en) 2] 4 [VNb 12 O 40 (VO) 2]· 13H 2 O (2)(en= ethylenediamine) …

Bridging linker installation strategy in the engineering of copper (ii) complexes: activation of nitriles, efficient catalysts for the cyanosilylation of aldehydes

AV Gurbanov, G Mahmoudi, E Zangrando, FI Zubkov… - …, 2024 - pubs.rsc.org
A series of bridging linkers such as pyrazine (L1), 4, 4′-bipyridine (L2),(E)-1, 2-di (pyridin-4-
yl) ethene (L3), 1, 2-di (pyridin-4-yl) ethane (L4), 1, 2-di (pyridin-4-yl) disulfane (L5), 1, 2-di …

Cyanosilylation of aldehydes catalyzed by ag (I)-and cu (ii)-arylhydrazone coordination polymers in conventional and in ionic liquid media

GAO Tiago, KT Mahmudov, MFC Guedes da Silva… - Catalysts, 2019 - mdpi.com
The novel Ag (I) and Cu (II) coordination polymers [Ag (μ 3-1κ O; 2: 3κ O′; 4κ N-HL)] n∙
n/2H2O (1) and [Cu (en) 2 (μ-1κ O; 2κ NL)] n∙ nH2O (2)[HL−= 2-(2-(1-cyano-2 …