Polyoxometalates: building blocks for functional nanoscale systems

DL Long, R Tsunashima… - Angewandte Chemie …, 2010 - Wiley Online Library
Polyoxometalates (POMs) are a subset of metal oxides that represent a diverse range of
molecular clusters with an almost unmatched range of physical properties and the ability to …

[HTML][HTML] The use of polyoxometalates in protein crystallography–An attempt to widen a well-known bottleneck

A Bijelic, A Rompel - Coordination Chemistry Reviews, 2015 - Elsevier
Polyoxometalates (POMs) are discrete polynuclear metal-oxo anions with a fascinating
variety of structures and unique chemical and physical properties. Their application in …

Highly stable crystalline catalysts based on a microporous metal− organic framework and polyoxometalates

CY Sun, SX Liu, DD Liang, KZ Shao… - Journal of the …, 2009 - ACS Publications
A series of remarkable crystalline compounds [Cu2 (BTC) 4/3 (H2O) 2] 6 [H n
XM12O40]·(C4H12N) 2 (X= Si, Ge, P, As; M= W, Mo) were obtained from the simple one …

Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism

YK Deng, HF Su, JH Xu, WG Wang… - Journal of the …, 2016 - ACS Publications
In search of functional molecular materials and the study of their formation mechanism, we
report the elucidation of a hierarchical step-by-step formation from monomer (Mn) to …

Polyoxometallate als Bausteine für funktionelle Nanosysteme

DL Long, R Tsunashima, L Cronin - Angewandte Chemie, 2010 - Wiley Online Library
Abstract Die Polyoxometallate (POM), eine Untergruppe der Metalloxide, bilden vielfältige
Molekülcluster, die nicht nur außerordentlich vielfältige physikalische Eigenschaften zeigen …

Evolutionary metal oxide clusters for novel applications: toward high‐density data storage in nonvolatile memories

X Chen, Y Zhou, VAL Roy, ST Han - Advanced Materials, 2018 - Wiley Online Library
Because of current fabrication limitations, miniaturizing nonvolatile memory devices for
managing the explosive increase in big data is challenging. Molecular memories constitute …

Old metal oxide clusters in new applications: spontaneous reduction of Keggin and Dawson polyoxometalate layers by a metallic electrode for improving efficiency in …

M Vasilopoulou, AM Douvas, LC Palilis… - Journal of the …, 2015 - ACS Publications
The present study is aimed at investigating the solid state reduction of a representative
series of Keggin and Dawson polyoxometalate (POM) films in contact with a metallic …

Cations in control: crystal engineering polyoxometalate clusters using cation directed self-assembly

CP Pradeep, DL Long, L Cronin - Dalton Transactions, 2010 - pubs.rsc.org
The synthetic engineering of anionic polyoxometalate (POM) clusters with predefined
properties tailored to specific applications is a great challenge using routine “one-pot” POM …

Real‐Time Observation of the Self‐Assembly of Hybrid Polyoxometalates Using Mass Spectrometry

EF Wilson, HN Miras, MH Rosnes… - Angewandte Chemie …, 2011 - Wiley Online Library
Polyoxometalate (POM) clusters constitute a wide and varied family of structures formed by
condensation reactions of metal oxide anions of early transition metals, for example, V, Mo …

Unravelling the complexities of inorganic and supramolecular self-assembly in solution with electrospray and cryospray mass spectrometry

HN Miras, EF Wilson, L Cronin - Chemical communications, 2009 - pubs.rsc.org
Electrospray (ESI) and cryospray mass spectrometry (CSI-MS) are proving to be
exceptionally versatile tools when used in conjunction with high resolution time-of-flight …