Enhanced basicity of push–pull nitrogen bases in the gas phase

ED Raczyńska, JF Gal, PC Maria - Chemical Reviews, 2016 - ACS Publications
Nitrogen bases containing one or more pushing amino-group (s) directly linked to a pulling
cyano, imino, or phosphoimino group, as well as those in which the pushing and pulling …

Nickel-Catalyzed Remote C(sp3)–N/O Bond Formation of Alkenes with Unactivated Amines and Alcohols

T Song, Y Luo, K Wang, B Wang, Q Yuan… - ACS Catalysis, 2023 - ACS Publications
Transition metal-catalyzed remote hydrofunctionalization of alkenes is an efficient method to
realize C (sp3)–H functionalization. However, remote hydrofunctionalization of alkenes with …

Modeling unimolecular reactions in photoelectron photoion coincidence experiments

B Sztáray, A Bodi, T Baer - Journal of mass spectrometry, 2010 - Wiley Online Library
A computer program has been developed to model and analyze the data from photoelectron
photoion coincidence (PEPICO) spectroscopy experiments. This code has been used during …

Heats of Formation of C6H5, C6H5+, and C6H5NO by Threshold Photoelectron Photoion Coincidence and Active Thermochemical Tables Analysis

WR Stevens, B Ruscic, T Baer - The Journal of Physical Chemistry …, 2010 - ACS Publications
Threshold photoelectron photoion coincidence has been used to prepare selected internal
energy distributions of nitrosobenzene ions [C6H5NO+]. Dissociation to C6H5++ NO …

Jet-stirred reactor study of low-temperature neopentane oxidation: a combined theoretical, chromatographic, mass spectrometric, and PEPICO analysis

J Bourgalais, O Herbinet, HH Carstensen… - Energy & …, 2021 - ACS Publications
The oxidation of neopentane was studied in jet-stirred reactors at atmospheric pressure over
a temperature range 500–850 K and ϕ= 0.5. The products were analyzed with …

Selective peroxidation of isobutane with molecular oxygen over molybdenum oxide catalyst for direct synthesis of di-tert-butyl peroxide

N Li, M Yuan, G Cui, J Xu, X Li, G Wang, X Zhu… - Chemical Engineering …, 2023 - Elsevier
The direct conversion of isobutane to high value-added chemicals is important for utilization
of C 4 hydrocarbon resources. This work proposed a novel route of isobutane peroxidation …

Kinetic Study of Di‐Tert‐Butyl Peroxide: Thermal Decomposition and Product Reaction Pathways

N Sebbar, JW Bozzelli… - International Journal of …, 2015 - Wiley Online Library
The major reaction path for oxidation of di‐tert‐butyl peroxide (DTBP) is generally
considered to occur via fission of the weak peroxide RO OR bond at temperatures above …

Pentadiynylidene and Its Methyl-Substituted Derivates: Threshold Photoelectron Spectroscopy of R1-C5-R2 Triplet Carbon Chains

E Reusch, D Kaiser, D Schleier… - The Journal of …, 2019 - ACS Publications
Mass-selective threshold photoelectron spectroscopy in the gas phase was employed to
characterize the dialkynyl triplet carbenes pentadiynylidene (HC5H) …

Unimolecular reaction mechanism of an imidazolin‐2‐ylidene: An iPEPICO study on the complex dissociation of an Arduengo‐type carbene

P Hemberger, A Bodi, T Gerber… - … A European Journal, 2013 - Wiley Online Library
The photoionization and dissociative photoionization of Im (iPr) 2, 1, 3‐diisopropylimidazolin‐
2‐ylidene, was investigated by imaging photoelectron photoion coincidence (iPEPICO) with …

Accounting for molecular flexibility in photoionization: case of tert-butyl hydroperoxide

J Bourgalais, Z Jiang, J Bloino, O Herbinet… - Physical Chemistry …, 2022 - pubs.rsc.org
tert-Butyl hydroperoxide (tBuOOH) is a common intermediate in the oxidation of organic
compounds that needs to be accurately quantified in complex gas mixtures for the …