Recent progress in synthetic applications of hypervalent iodine (III) reagents

A Yoshimura, VV Zhdankin - Chemical Reviews, 2024 - ACS Publications
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

Iodine (V)-Based Oxidants in Oxidation Reactions

SE Shetgaonkar, S Jothish, T Dohi, FV Singh - Molecules, 2023 - mdpi.com
The chemistry of hypervalent iodine reagents has now become quite valuable due to the
reactivity of these compounds under mild reaction conditions and their resemblance in …

Phenyliodine (III) diacetate (PIDA): applications in rearrangement/migration reactions

MM Alam, HB Bollikolla, M Amanullah… - Current Organic …, 2023 - benthamdirect.com
One of the most widely utilized hypervalent iodines used as an oxidizing agent in organic
chemistry is (dialcetoxyiodo) benzene (PhI (OAc) 2), also known as (DAIB), phenyliodine (III) …

Base-Mediated Visible-Light-Driven C–H Arylation of Quinoxalin-2(1H)-Ones in Ethanol

Y Pan, L Wang, Y Shi, G Huang, X Bu… - The Journal of …, 2024 - ACS Publications
Prior methods for visible-light-driven C–H arylation of quinoxalin-2 (1 H)-ones relied on
external photocatalysts. Herein, we report a photocatalyst-free approach for this arylation. In …

Catalytic stereoselective synthesis involving hypervalent iodine-based chiral auxiliaries

SE Shetgaonkar, FV Singh - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
Hypervalent iodine catalysis is one of the fast growing research areas of hypervalent iodine
chemistry. In recent years, the attention of several hypervalent iodine chemists has moved …

Dess-Martin Periodinane (DMP) in organic synthesis-a septennial update (2015-till date)

R Varala, V Seema, MM Alam… - Current Organic …, 2023 - benthamdirect.com
Dess-Martin periodinane (DMP) is one of the hypervalent iodines that is most frequently
utilized as an oxidizing agent in organic chemistry. The authors of this septennial review …

Recent Advances in the Synthesis of 3, n-Fused Tricyclic Indole Skeletons via Palladium-Catalyzed Domino Reactions

L Fan, X Zhu, X Liu, F He, G Yang, C Xu, X Yang - Molecules, 2023 - mdpi.com
3, n-fused (n= 4–7) tricyclic indoles are pervasive motifs, embedded in a variety of
biologically active molecules and natural products. Thus, numerous catalytic methods have …

Iodoxybenzoic Acid (IBX) in Organic Synthesis: A Septennial Review

R Varala, V Seema, MM Alam, N Dubasi… - Current Organic …, 2024 - ingentaconnect.com
This study reviews the oxidative applications of 2-iodoxybenzoic acid (IBX) in organic
synthesis, focusing on CH functionalization, hetero-hetero bond formations, ring cleavage …

Applications of phenyliodine (III) diacetate in heterocyclic ring formations: An update from 2015 to date

MM Alam, M Hussien, HB Bollikolla… - Journal of …, 2023 - Wiley Online Library
Abstract Diacetoxyiodobenzene (PhI (OAc) 2), commonly referred to as DAIB or
phenyliodine (III) diacetate (PIDA), is one of the most frequently used hypervalent iodines …

Design, development and applications of copper-catalyzed regioselective (4+ 2) annulations between diaryliodonium salts and alkynes

W Wang, J Zhou, C Wang, C Zhang… - Communications …, 2022 - nature.com
Diaryliodonium salts have been extensively applied in organic synthesis as aryl cation
equivalents. However, in the electrophilic reactions with alkenes or alkynes, only the …