Since its early days, olefin metathesis has been in the focus of scientific discussions and
technology development. While heterogeneous olefin metathesis catalysts based on …

Cationic d0 group 6 olefin metathesis catalysts have been recently shown to display in most
instances superior activity in comparison to their neutral congeners. Furthermore, their …

The catalytic performances of molecular and silica-supported molybdenum oxo alkylidene
species bearing anionic O ligands [ORF9, OTPP, OHMT–where ORF9= OC (CF3) 3, OTPP …

We recently reported a method for selective macro (mono) cyclization of dienes utilizing
catalysts confined inside the pores of mesoporous silica, which we believe occurs due to …

Macrocyclization reactions are still challenging due to competing oligomerization, which
requires the use of small substrate concentrations. Here, the cationic tungsten imido and …

Tailored molybdenum (VI)‐oxo complexes of the form MoOCl2 (OR) 2 (OEt2) catalyse olefin
metathesis upon reaction with an organosilicon reducing agent at 70° C, in the presence of …

The syntheses of the neutral molybdenum imido alkylidene N‐heterocyclic carbene (NHC)
complexes of the general formula [Mo (NAr)(CHCMe2Ph)(NHC) XY](Ar= 2‐tBu‐C6H4, 2 …

Molybdenum imido adamantylidene complexes with different substituents on the imido
ligand (dipp= 2, 6‐diisopropylphenyl, ArF5= C6F5, and tBu) having distinct electron …

Tungsten oxo adamantylidenes (= Ad) are a new class of readily accessible alkylidenes, that
opens the possibility to evaluate a broader class of molecular and supported olefin …

Nach einer langen angenehmen gemeinsamen Zeit mit vielen Herausforderungen und
spannenden Erkenntnissen möchte ich mich bei Prof. Dr. Michael R. Buchmeiser für sein …