The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …

The presence of site-isolated and well-defined metal sites has enabled the use of metal–
organic frameworks (MOFs) as catalysts that can be rationally modulated. Because MOFs …

Ammonia is regarded as an energy vector for hydrogen storage, transport and utilization,
which links to usage of renewable energies. However, efficient catalysts for ammonia …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

Nitrogen fixation is essential for the maintenance of life and development of society,
however, the large bond dissociation energy and nonpolarity of the triple bond constitute a …

Recent advances in catalytic nitrogen fixation using well-defined molecular transition metal–
dinitrogen complexes and their precursors as catalysts under ambient or mild reaction …

Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …

The activation of dinitrogen (N2) by transition metals is central to the highly energy intensive,
heterogeneous Haber–Bosch process. Considerable progress has been made towards …

The Fe–S clusters of nitrogenases carry out the life-sustaining conversion of N2 to NH3.
Although progress continues to be made in modelling the structural features of nitrogenase …

The catalytic transformation of N2 to NH3 by transition metal complexes is of great interest
and importance but has remained a challenge to date. Despite the essential role of …