The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
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Polypyridyl transition metal complexes represent one of the more thoroughly studied classes
of molecular catalysts towards CO2 reduction to date. Initial reports in the 1980s began with …

With the goal of improving previously reported Mn bipyridine electrocatalysts in terms of
increased activity and reduced overpotential, a bulky bipyridine ligand, 6, 6′-dimesityl-2 …

Modern energy challenges have amplified interest in transition metal-based molecular
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …

[Re (bpy)(CO) 3]− is a well-established homogeneous electrocatalyst for the reduction of
CO2 to CO. Recently, substitution of the more abundant transition metal Mn for Re yielded a …

A complete mechanism for the proton-dependent electrocatalytic reduction of CO2 to CO by
fac-Re (bpy)(CO) 3Cl that is consistent with experimental observations has been developed …

The use of infrared spectroelectrochemistry (IR-SEC) as a characterization method for
molecular electrocatalysts allows researchers to identify key intermediates and products …

Attaching the phosphonated molecular catalyst [ReIBr (bpy)(CO) 3] 0 to the wide-bandgap
semiconductor TiO2 strongly enhances the rate of visible-light-driven reduction of CO2 to …

The electrochemical behavior of fac‐[Mn (pdbpy)(CO) 3Br](pdbpy= 4‐phenyl‐6‐(phenyl‐2, 6‐
diol)‐2, 2′‐bipyridine)(1) in acetonitrile under Ar, and its catalytic performances for CO2 …