The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Asymmetric catalysis has emerged as a general and powerful approach for constructing
chiral compounds in an enantioselective manner. Hence, developing novel chiral ligands …

An enantioselective protonation strategy has been successfully applied to the synthesis of
chiral α-tertiary azaarenes. With a dual catalytic system involving a chiral phosphoric acid …

A radical-based asymmetric olefin difunctionalization strategy for rapidly forging all-carbon
quaternary stereocenters α to diverse azaarenes is reported. Under cooperative photoredox …

A nickel hydride-catalyzed regio-and enantioselective hydroalkylation reaction was
developed to give access to a library of chiral β-or γ-branched aromatic N-heterocycles. This …

Rhodium-catalyzed asymmetric arylation (RCAA) reactions provide one of the most
straightforward and powerful ways to introduce aryl fragments in an enantioselective …

A novel enantioselective protonation protocol that is triggered by reductive cross coupling of
olefins is reported. When under cooperative photoredox and chiral hydrogen-bonding …

This paper describes a highly enantioselective metal-free hydrogenation of imines using
chiral dienes as “ligands” for the generation of catalysts with HB (C6F5) 2 by hydroboration …

A visible light‐induced Co‐catalyzed highly regio‐and stereoselective reductive coupling of
vinyl azaarenes and alkynes has been developed. Notably, Hünig's base together with …

We report a highly enantioselective Pd–PHOX-catalyzed intermolecular hydroalkylation of
acyclic 1, 3-dienes. Meldrum's acid derivatives and other activated C-pronucleophiles, such …