Oxygen activation and radical transformations in heme proteins and metalloporphyrins
As a result of the adaptation of life to an aerobic environment, nature has evolved a panoply
of metalloproteins for oxidative metabolism and protection against reactive oxygen species …
of metalloproteins for oxidative metabolism and protection against reactive oxygen species …
Structure and function of haemoglobins
DA Gell - Blood Cells, Molecules, and Diseases, 2018 - Elsevier
Haemoglobin (Hb) is widely known as the iron-containing protein in blood that is essential
for O 2 transport in mammals. Less widely recognised is that erythrocyte Hb belongs to a …
for O 2 transport in mammals. Less widely recognised is that erythrocyte Hb belongs to a …
Synthetic Fe/Cu complexes: toward understanding heme-copper oxidase structure and function
Heme-copper oxidases (HCOs) are terminal enzymes on the mitochondrial or bacterial
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …
K-and L-edge X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) determination of differential orbital covalency (DOC) of transition …
ML Baker, MW Mara, JJ Yan, KO Hodgson… - Coordination chemistry …, 2017 - Elsevier
Continual advancements in the development of synchrotron radiation sources have resulted
in X-ray based spectroscopic techniques capable of probing the electronic and structural …
in X-ray based spectroscopic techniques capable of probing the electronic and structural …
Probing the active site in single-atom oxygen reduction catalysts via operando X-ray and electrochemical spectroscopy
Nonnoble metal catalysts are low-cost alternatives to Pt for the oxygen reduction reactions
(ORRs), which have been studied for various applications in electrocatalytic systems …
(ORRs), which have been studied for various applications in electrocatalytic systems …
Metal–organic frameworks as O 2-selective adsorbents for air separations
Oxygen is a critical gas in numerous industries and is produced globally on a gigatonne
scale, primarily through energy-intensive cryogenic distillation of air. The realization of large …
scale, primarily through energy-intensive cryogenic distillation of air. The realization of large …
Probing the oxidation state of transition metal complexes: a case study on how charge and spin densities determine Mn L-edge X-ray absorption energies
Transition metals in inorganic systems and metalloproteins can occur in different oxidation
states, which makes them ideal redox-active catalysts. To gain a mechanistic understanding …
states, which makes them ideal redox-active catalysts. To gain a mechanistic understanding …
Applications of large-scale density functional theory in biology
Density functional theory (DFT) has become a routine tool for the computation of electronic
structure in the physics, materials and chemistry fields. Yet the application of traditional DFT …
structure in the physics, materials and chemistry fields. Yet the application of traditional DFT …
Discovery of the magnetic behavior of hemoglobin: A beginning of bioinorganic chemistry
Two articles published by Pauling and Coryell in PNAS nearly 80 years ago described in
detail the magnetic properties of oxy-and deoxyhemoglobin, as well as those of closely …
detail the magnetic properties of oxy-and deoxyhemoglobin, as well as those of closely …