Copper-catalyzed carbonylative coupling of alkyl halides

LJ Cheng, NP Mankad - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Transition metal-catalyzed carbonylation reactions represent a direct and atom-
economical approach to introduce oxygen functionality into organic compounds, with CO …

C–C and C–X coupling reactions of unactivated alkyl electrophiles using copper catalysis

LJ Cheng, NP Mankad - Chemical Society Reviews, 2020 - pubs.rsc.org
Transition metal-catalysed cross-coupling reactions are widely used for construction of
carbon–carbon and carbon–heteroatom bonds. However, compared to aryl or alkenyl …

Visible-light-induced iron-catalyzed synthesis of N-aryl amides from nitroarenes and chloroalkanes

QL Zhang, W Liu, Y Zhou, FL Zhang - Green Chemistry, 2023 - pubs.rsc.org
An unprecedented straightforward reductive amidation of chloroalkanes with nitroarenes
was readily accomplished by merging iron catalysis with visible-light photoredox catalysis. A …

Molybdenum-Catalyzed Reductive Ortho-Allylation of Nitroarenes with 1,3-Dienes

JL Lu, Z Zhang, JT Deng, JB Peng - ACS Catalysis, 2024 - ACS Publications
The direct catalytic reductive functionalization of nitroarenes to produce amines with
enhanced properties continues to attract attention for both academic and industrial …

Light-mediated synthesis of aliphatic anhydrides by Cu-catalyzed carbonylation of alkyl halides

P Tung, NP Mankad - Journal of the American Chemical Society, 2023 - ACS Publications
Acid anhydrides are valuable in the chemical industry for their role in synthesizing polymers,
pharmaceuticals, and other commodities, but their syntheses often involve multiple steps …

B2(OH)4-Mediated Reductive Transamidation of N-Acyl Benzotriazoles with Nitro Compounds En Route to Aqueous Amide Synthesis

J Bai, S Li, R Zhu, Y Li, W Li - The Journal of Organic Chemistry, 2023 - ACS Publications
We herein developed a reductive transamidation reaction between N-acyl benzotriazoles
(AcBt) and organic nitro compounds or NaNO2 under mild conditions. This protocol …

Molybdenum-mediated reductive deuteration of nitroarenes with D 2 O: synthesis of ortho-and para-deuterated anilines

JL Lu, JT Deng, M Lang, JB Peng - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
A unique and practical molybdenum-mediated reductive deuteration of nitroarenes for the
selective synthesis of ortho-and para-deuterated anilines has been developed. Using Mo …

Visible-Light- and PPh3-Mediated Direct C–N Coupling of Nitroarenes and Boronic Acids at Ambient Temperature

K Manna, T Ganguly, S Baitalik, R Jana - Organic Letters, 2021 - ACS Publications
We present here a metal-free, visible-light-and triphenylphosphine-mediated intermolecular,
reductive amination between nitroarenes and boronic acids at ambient temperature without …

Recent Advances in Base‐Metal‐Catalyzed Carbonylation of Unactivated Alkyl Electrophiles

W Li, D Jiang, C Wang, LJ Cheng - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary Transition metal‐catalyzed carbonylation reactions represent a
direct and atom‐economical approach to synthesize carbonyl compounds or their …

Nickel-Catalyzed Arylcarbamoylation of Alkenes of N-(o-Iodoaryl)acrylamides with Nitroarenes via Reductive Aminocarbonylation: Facile Synthesis of Carbamoyl …

C Cheng, JN Xiang, YP Zhu, ZH Peng, JH Li - Organic Letters, 2021 - ACS Publications
Nickel-catalyzed arylcarbamoylation reactions of alkenes of N-(o-haloaryl) acrylamides with
CO and nitroarenes via reductive aminocarbonylation to produce carbamoyl-substituted …