Transition-metal complexes are attractive targets for the design of catalysts and functional
materials. The behavior of the metal–organic bond, while very tunable for achieving target …

This review highlights in situ UV–vis–NIR range absorption spectroscopy in catalysis. A
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …

The relationship between chemical structure and spin state in a transition metal complex has
an important bearing on mechanistic bioinorganic chemistry, catalysis by base metals, and …

Bis (formazanate) iron (II) complexes undergo a thermally induced S= 0 to S= 2 spin
transition in solution. Here we present a study of how steric effects and π-stacking …

An electrochemical cell consisting of cobalt ([CoII/III (P3O9) 2] 4–/3–) and vanadium ([VIII/II
(P3O9) 2] 3–/4–) bistrimetaphosphate complexes as catholyte and anolyte species …

The transition between spin states in d-block metal complexes has important ramifications
for their structure and reactivity, with applications ranging from information storage materials …

A new synthetic pathway is devised to selectively produce previously elusive heteroleptic
iron (II) complexes of terpyridine and N, N′-disubstituted bis (pyrazol-3-yl) pyridines that …

Spin transitions in spin-crossover compounds are now routinely studied in the solid state by
magnetometry; however, only a few methods exist for studies in solution. The currently used …

Nonheme iron oxygenases utilize dioxygen to accomplish challenging chemical oxidations.
A further understanding of the Fe–O2 intermediates implicated in these processes is …

Here we report the first successful attempt to identify spin-crossover compounds in solutions
of metal complexes produced by mixing different ligands and an appropriate metal salt by …