The theory and practice of hyperpolarization in magnetic resonance using parahydrogen

RA Green, RW Adams, SB Duckett, RE Mewis… - Progress in nuclear …, 2012 - Elsevier
NMR spectroscopy is arguably the most powerful and versatile analytical spectroscopic
method available to analyze nuclides which possess a magnetic dipole moment and …

Heterogeneous Catalysis and Parahydrogen‐Induced Polarization

EV Pokochueva, DB Burueva, OG Salnikov… - …, 2021 - Wiley Online Library
Parahydrogen‐induced polarization with heterogeneous catalysts (HET‐PHIP) has been a
subject of extensive research in the last decade since its first observation in 2007. While …

Strongly luminescent InP/ZnS core-shell nanoparticles.

S Haubold, M Haase, A Kornowski… - … : a European Journal of …, 2001 - europepmc.org
The wide-bandgap semiconducting material, zinc sulfide, has been coated on indium
phosphide nanoclusters to a 1-2-Å thickness. The resulting InP-ZnS core-shell particle (as …

Mechanism of Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (S,S)-1,2-Bis(tert-butylmethylphosphino)ethane. Dihydride Mechanism of Asymmetric …

ID Gridnev, N Higashi, K Asakura… - Journal of the American …, 2000 - ACS Publications
The mechanism of asymmetric hydrogenation catalyzed by a new effective catalyst, viz., a
rhodium complex of (S, S)-1, 2-bis (tert-butylmethylphosphino) ethane (BisP*), has been …

para-Hydrogen-Induced Polarization in Heterogeneous Hydrogenation Reactions

IV Koptyug, KV Kovtunov, SR Burt… - Journal of the …, 2007 - ACS Publications
We demonstrate the creation and observation of para-hydrogen-induced polarization in
heterogeneous hydrogenation reactions. Wilkinson's catalyst, RhCl (PPh3) 3, supported on …

Synergies between hyperpolarized NMR and microfluidics: a review

J Eills, W Hale, M Utz - Progress in Nuclear Magnetic Resonance …, 2022 - Elsevier
Hyperpolarized nuclear magnetic resonance and lab-on-a-chip microfluidics are two
dynamic, but until recently quite distinct, fields of research. Recent developments in both …

Parahydrogen-based NMR methods as a mechanistic probe in inorganic chemistry

SB Duckett, NJ Wood - Coordination Chemistry Reviews, 2008 - Elsevier
The study of reactions by NMR spectroscopy is normally limited by the poor detection limits
offered by the method. An overview is presented of how chemical reactions can be studied …

Para-hydrogen induced polarization of amino acids, peptides and deuterium–hydrogen gas

S Glöggler, R Müller, J Colell, M Emondts… - Physical Chemistry …, 2011 - pubs.rsc.org
Signal Amplification by Reversible-Exchange (SABRE) is a method of hyperpolarizing
substrates by polarization transfer from para-hydrogen without hydrogenation. Here, we …

Single‐atom gold catalysis in the context of developments in parahydrogen‐induced polarization

A Corma, OG Salnikov, DA Barskiy… - … A European Journal, 2015 - Wiley Online Library
A highly isolated monoatomic gold catalyst, with single gold atoms dispersed on multiwalled
carbon nanotubes (MWCNTs), has been synthesized, characterized, and tested in …

Para‐hydrogen‐enhanced hyperpolarized gas‐phase magnetic resonance imaging

LS Bouchard, KV Kovtunov, SR Burt… - Angewandte Chemie …, 2007 - Wiley Online Library
Herein, we demonstrate magnetic resonance imaging (MRI)[1] in the gas phase using para-
hydrogen (pH 2)-induced polarization.[2] A reactant mixture of H2 enriched in the para spin …