Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …

Fluorine has received great attention in all fields of science.“Small atom with a big ego” was
the title of the Symposium at the ACS meeting in San Francisco in 2000, where a number of …

A catalytic protocol to convert aryl and heteroaryl chlorides to the corresponding
trifluoromethyl sulfides is reported herein. It relies on a relatively inexpensive Ni (cod) 2/dppf …

In this Account, we describe the transition metal-mediated cleavage of C− F and C− H bonds
in fluoroaromatic and fluoroheteroaromatic molecules. The simplest reactions of …

The synthesis of organic compounds efficiently via fewer steps but in higher yields is
desirable as this reduces energy and reagent use, waste production, and thus …

The presence of heterocyclic moieties in all kinds of organic compounds of interest in
biology, pharmacology, optics, electronics, material sciences, and so on is sufficiently known …

The first systematic mechanism study of C− F reductive elimination from a transition metal
complex is described. C− F bond formation from three different Pd (IV) fluoride complexes …

The NHC‐stabilized complex [Ni2 (iPr2Im) 4 (cod)](1) was isolated in good yield from the
reaction of [Ni (cod) 2] with 1, 3‐diisopropylimidazole‐2‐ylidene (iPr2Im). Compound 1 is a …

Nickel catalysts derived from bis (1, 5‐cyclooctadiene) nickel [Ni (cod) 2] and
trialkylphosphines effect hydroarylation of alkynes through functionalization of C–H bonds of …