Homogeneous gold catalysis has experienced extraordinary development since the dawn of
this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the …

Catalytic transformations involving metal carbenes are considered one of the most important
aspects of homogeneous transition metal catalysis. Recently, gold-catalyzed generation of …

Nitrones are important compounds and are highly useful in many aspects. The first part
describes the methods for synthesis of nitrones, which are useful and environmentally …

Multicomponent reactions that involve interception of onium ylides through Aldol, Mannich,
and Michael addition with corresponding bench-stable acceptors have demonstrated broad …

Catalytic oxidative functionalization of alkynes has emerged as an effective method in
synthetic chemistry in recent decades. However, enantioselective transformations via metal …

Herein, we report an achiral dirhodium complex and chiral phosphoric acid cooperatively
catalyzed asymmetric three-component reaction of enynal with alcohol and imine, affording …

Alkynes represent a family of pivotal and sustainable feedstocks for various industries such
as pharmaceuticals, agrochemicals, and materials, and they are widely used as important …

Enantioselective α-aminomethylation of carbonyl compounds constitutes a powerful protocol
for introducing aminomethyl groups to simple organic molecules. However, current …

Homogeneous gold catalysis has demonstrated the preponderant capability of realizing a
broad range of synthetically versatile alkyne functionalization over the last two decades …

An asymmetric para‐C (sp2)− H bond functionalization of alkyl benzene derivatives was
successfully developed via cooperative catalysis of gold and chiral phosphoric acid (CPA) …