Steering On-Surface Reactions by Kinetic and Thermodynamic Strategies
On-surface synthesis has emerged as a powerful tool to fabricate various functional low-
dimensional nanostructures with atomic precision, thus becoming a promising platform for …
dimensional nanostructures with atomic precision, thus becoming a promising platform for …
On-surface synthesis toward two-dimensional polymers
Two-dimensional (2D) polymers have garnered widespread interest because of their
intriguing physicochemical properties. Envisaged applications in fields including …
intriguing physicochemical properties. Envisaged applications in fields including …
Selective Activation of Aromatic C–H Bonds Catalyzed by Single Gold Atoms at Room Temperature
Selective activation and controlled functionalization of C–H bonds in organic molecules is
one of the most desirable processes in synthetic chemistry. Despite progress in …
one of the most desirable processes in synthetic chemistry. Despite progress in …
Highly Regioselective Cyclodehydrogenation of Diphenylporphyrin on Metal Surfaces
Y Zhang, J Lu, H Zhou, G Zhang, Z Ruan, Y Zhang… - ACS …, 2023 - ACS Publications
Exploring the effect of porphin tautomerism on the regioselectivity of its derivatives is a big
challenge, which is significant for the development and application of porphyrin drugs. In this …
challenge, which is significant for the development and application of porphyrin drugs. In this …
Surface-confined alternating copolymerization with molecular precision by stoichiometric control
L Xing, J Li, Y Bai, Y Lin, L Xiao, C Li, D Zhao… - Nature …, 2024 - nature.com
Keen desires for artificial mimicry of biological polymers and property improvement of
synthesized ones have triggered intensive explorations for sequence-controlled …
synthesized ones have triggered intensive explorations for sequence-controlled …
Atomically precise imprinting π-magnetism in nanographenes via probe chemistry
The precise generation and harnessing of carbon magnetism at the single-molecule level
have been captivating areas of research in chemistry and nanotechnology. However, the …
have been captivating areas of research in chemistry and nanotechnology. However, the …
Structural, electronic, and vibrational properties of a two-dimensional graphdiyne-like carbon nanonetwork synthesized on Au (111): implications for the engineering of …
Graphdiyne, atomically thin two-dimensional (2D) carbon nanostructure based on sp-sp2
hybridization is an appealing system potentially showing outstanding mechanical and …
hybridization is an appealing system potentially showing outstanding mechanical and …
Topology Selectivity in On-Surface Dehydrogenative Coupling Reaction: Dendritic Structure versus Porous Graphene Nanoribbon
Selective control on the topology of low-dimensional covalent organic nanostructures in on-
surface synthesis has been challenging. Herein, with combined scanning tunneling …
surface synthesis has been challenging. Herein, with combined scanning tunneling …
On‐Surface Synthesis of [3] Radialenes via [1+ 1+ 1] Cycloaddition
DY Li, Y Wang, XY Hou, YT Ren, LX Kang… - Angewandte …, 2022 - Wiley Online Library
Radialenes are the smallest carbocyclic structures with unusual topologies and cross‐
conjugated π‐electronic structures. Here, we report a novel [1+ 1+ 1] cycloaddition reaction …
conjugated π‐electronic structures. Here, we report a novel [1+ 1+ 1] cycloaddition reaction …
On-surface synthesis of self-assembled covalently linked wavy chains with site-selective conformational switching
L Wang, R Zhu, Z Shen, Y Song, L She… - Journal of the …, 2023 - ACS Publications
Conformational arrangements in polymers on surfaces determine the overall shape as well
as the potential properties. It is generally believed that conformational diversity leads to …
as the potential properties. It is generally believed that conformational diversity leads to …