Polyelectrolyte brushes

M Ballauff, O Borisov - Current Opinion in Colloid & Interface Science, 2006 - Elsevier
We survey recent progress made in the field of polyelectrolyte brushes. These systems
consist of long polyelectrolyte chains that are grafted densely to planar or curved surfaces …

Spherical polyelectrolyte brushes

M Ballauff - Progress in Polymer Science, 2007 - Elsevier
We review recent work on colloidal particles bearing a dense layer of linear polyelectrolyte
chains on their surface. These systems have been termed “spherical polyelectrolyte …

High catalytic activity of platinum nanoparticles immobilized on spherical polyelectrolyte brushes

Y Mei, G Sharma, Y Lu, M Ballauff, M Drechsler… - Langmuir, 2005 - ACS Publications
We present a study on the catalytic activity of platinum nanoparticles immobilized on
spherical polyelectrolyte brushes that act as carriers. The spherical polyelectrolyte brushes …

Adsorption of proteins on spherical polyelectrolyte brushes in aqueous solution

A Wittemann, B Haupt, M Ballauff - Physical Chemistry Chemical …, 2003 - pubs.rsc.org
We consider the adsorption of bovine serum albumin (BSA) on spherical polyelectrolyte
brushes (SPB). The SPB consist of a solid polystyrene core of 100 nm diameter onto which …

Synthesis, characterization and behavior in aqueous solution of star‐shaped poly (acrylic acid)

FA Plamper, H Becker, M Lanzendörfer… - Macromolecular …, 2005 - Wiley Online Library
We report the synthesis of star‐shaped poly (acrylic acid)(PAA), with 5, 8, and 21 arms, by
atom transfer radical polymerization of tert‐butyl acrylate. We employ the core‐first approach …

Interaction of proteins with linear polyelectrolytes and spherical polyelectrolyte brushes in aqueous solution

A Wittemann, M Ballauff - Physical Chemistry Chemical Physics, 2006 - pubs.rsc.org
We review recent experiments on the interaction of proteins with anionic polyelectrolytes in
aqueous solution. Data from the literature demonstrate that proteins can form soluble …

'Nano-tree'—type spherical polymer brush particles as templates for metallic nanoparticles

Y Lu, Y Mei, R Walker, M Ballauff, M Drechsler - Polymer, 2006 - Elsevier
We present a new type of spherical polymer brush particles that consist of a solid poly
(styrene) core (diameter: ca. 100nm) onto which chains of a bottlebrush polymer have been …

Cationic spherical polyelectrolyte brushes as nanoreactors for the generation of gold particles

G Sharma, M Ballauff - Macromolecular rapid communications, 2004 - Wiley Online Library
If long polyelectrolyte chains are attached densely to colloidal latex particles, a spherical
polyelectrolyte brush results. These spherical polyelectrolytes are dispersed in water and …

Activity of enzymes immobilized in colloidal spherical polyelectrolyte brushes

B Haupt, T Neumann, A Wittemann… - …, 2005 - ACS Publications
We investigate the enzymatic activity of glucoamylase and β-glucosidase adsorbed on a
novel type of colloidal particles. The particles used consist of a poly (styrene) core onto …

Interaction of proteins with spherical polyelectrolyte brushes in solution as studied by small-angle x-ray scattering

S Rosenfeldt, A Wittemann, M Ballauff… - Physical Review E …, 2004 - APS
We use small-angle x-ray scattering (SAXS) as a tool to study the binding of proteins to
spherical polyelectrolyte brushes (SPB) in situ. The SPB consists of a solid core of∼ 100 nm …