We report the first synthesis and structural characterization of free, uncomplexed phosphet-2-
ones. These unsaturated four-membered phosphacycles were prepared by phosphinidene …

Phosphanorcaradienes are an appealing class of phosphorus compounds that can serve as
synthons of transient phosphinidenes. However, the synthesis of such species is a …

Phosphinidenes are heavy congeners of nitrenes that have been broadly used as in situ
reagents in synthetic phosphorus chemistry and also serve as versatile ligands in …

We expand upon the synthetic utility of anionic rhenium complex Na [(BDI) ReCp](1, BDI= N,
N'-bis (2, 6-diisopropylphenyl)-3, 5-dimethyl-β-diketiminate) to generate several rhenium …

Herein, we report boron-centered arene extrusion reactions to afford putative cyclic
(alkyl)(amino) carbene (CAAC)-ligated chloroborylene and bromoborylene intermediates …

The direct chlorine-free incorporation of P1 units into organic molecules has very important
synthetical value owing to environmental considerations and the prospect of accessing …

Herein we report straightforward synthesis, characterization and reactivity studies of a
phosphanorcaradiene, in which one of the benzene rings in the flanking fluorenyl …