Aqueous alteration of silicate glass: state of knowledge and perspectives

S Gin, JM Delaye, F Angeli, S Schuller - npj Materials Degradation, 2021 - nature.com
The question of silicate glass chemical durability is at the heart of many industrial and
environmental issues, with certain glasses, such as bioglasses, needing to transform rapidly …

Forty years of durability assessment of nuclear waste glass by standard methods

CL Thorpe, JJ Neeway, CI Pearce, RJ Hand… - npj Materials …, 2021 - nature.com
Standard methods to assess the durability of vitrified radioactive waste were first developed
in the 1980's and, over the last 40 years, have evolved to yield a range of responses …

A comparative review of the aqueous corrosion of glasses, crystalline ceramics, and metals

GS Frankel, JD Vienna, J Lian, JR Scully, S Gin… - npj Materials …, 2018 - nature.com
All materials can suffer from environmental degradation; the rate and extent of degradation
depend on the details of the material composition and structure as well as the environment …

Recent advances in corrosion science applicable to disposal of high-level nuclear waste

GS Frankel, JD Vienna, J Lian, X Guo, S Gin… - Chemical …, 2021 - ACS Publications
High-level radioactive waste is accumulating at temporary storage locations around the
world and will eventually be placed in deep geological repositories. The waste forms and …

[HTML][HTML] Hanford low-activity waste vitrification: a review

J Marcial, BJ Riley, AA Kruger, CE Lonergan… - Journal of Hazardous …, 2024 - Elsevier
This paper summarizes the vast body of literature (over 200 documents) related to
vitrification of the low-activity waste (LAW) fraction of the Hanford tank wastes. Details are …

[HTML][HTML] Data-driven machine learning for disposal of high-level nuclear waste: A review

G Hu, W Pfingsten - Annals of Nuclear Energy, 2023 - Elsevier
The application of the data-driven machine learning (DDML) for the disposal of the high-
level nuclear waste (HLW) is of emerging interest in the recent years. This review aims to …

Deciphering the non-linear impact of Al on chemical durability of silicate glass

K Damodaran, JM Delaye, AG Kalinichev, S Gin - Acta Materialia, 2022 - Elsevier
The role of Al in aluminosilicate glasses remains somewhat a mystery: at low concentrations,
it increases the resistance to hydrolysis of the glass, whereas at high concentrations an …

Impacts of glass composition, pH, and temperature on glass forward dissolution rate

JD Vienna, JJ Neeway, JV Ryan, SN Kerisit - npj Materials degradation, 2018 - nature.com
Nuclear waste glasses dissolve at the forward dissolution rate (rf) in very dilute aqueous
solutions, which can isolate the impact of the glass composition from solution feedback and …

Effect of composition on the corrosion behavior of 24 statistically-designed alkali-borosilicate waste glasses

JJ Neeway, JT Reiser, SN Kerisit, RA Reyes… - Journal of Nuclear …, 2023 - Elsevier
The extent of glass dissolution is dependent on time, temperature, solution chemistry, and
the glass composition, among other factors. To obtain an understanding of the relative …

Effects of Al: Si and (Al+ Na): Si ratios on the properties of the international simple glass, part II: Structure

X Lu, JT Reiser, B Parruzot, L Deng… - Journal of the …, 2021 - Wiley Online Library
High‐alumina containing high‐level waste (HLW) will be vitrified at the Waste Treatment
Plant at the Hanford Site. The resulting glasses, high in alumina, will have distinct …