Perspectives in chemistry—steps towards complex matter

JM Lehn - Angewandte Chemie International Edition, 2013 - Wiley Online Library
Chemistry is progressively unraveling the processes that underlie the evolution of matter
towards states of higher complexity and the generation of novel features along the way by …

Solution behaviors and self-assembly of polyoxometalates as models of macroions and amphiphilic polyoxometalate–organic hybrids as novel surfactants

P Yin, D Li, T Liu - Chemical Society Reviews, 2012 - pubs.rsc.org
Large, hydrophilic polyoxoanions with high solubility in water and/or other polar solvents
demonstrate unique solution behavior by self-assembling into single layer, hollow, spherical …

From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry

A Müller, P Gouzerh - Chemical Society Reviews, 2012 - pubs.rsc.org
Following Nature's lessons, today chemists can cross the boundary of the small molecule
world to construct multifunctional and highly complex molecular nano-objects up to protein …

The Gigantic {Ni36Gd102} Hexagon: A Sulfate-Templated “Star-of-David” for Photocatalytic CO2 Reduction and Magnetic Cooling

WP Chen, PQ Liao, PB Jin, L Zhang… - Journal of the …, 2020 - ACS Publications
Gigantic coordination molecules assembled from a large number of metal ions and organic
ligands are structurally and functionally challenging to characterize. Here we show that a …

A polyoxometalate cluster paradigm with self-adaptive electronic structure for acidity/reducibility-specific photothermal conversion

C Zhang, W Bu, D Ni, C Zuo, C Cheng… - Journal of the …, 2016 - ACS Publications
Photothermal conversion is one of the most important keys in the fields of solar collection,
photo-hyperthermia, etc., and its performance is highly dependent on the photothermal …

Polyoxometalate-decorated nanoparticles

Y Wang, IA Weinstock - Chemical Society Reviews, 2012 - pubs.rsc.org
Polyoxometalate cluster anions (POMs) control formation and morphology, and serve as
protecting ligands, for structurally and compositionally diverse nanostructures. While …

Structural Evolution of Giant Polyoxometalate: From “Keplerate” to “Lantern” Type Mo132 for Improved Oxidation Catalysis

J Liu, N Jiang, JM Lin, ZB Mei, LZ Dong… - Angewandte …, 2023 - Wiley Online Library
Structural variants of high‐nuclearity clusters are extremely important for their modular
assembly study and functional expansion, yet the synthesis of such giant structural variants …

Ionic complexes of metal oxide clusters for versatile self-assemblies

B Li, W Li, H Li, L Wu - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus The combination of rational design of building components and suitable
utilization of driving force affords spontaneous molecular assemblies with well-defined …

Bioresponsive polyoxometalate cluster for redox-activated photoacoustic imaging-guided photothermal cancer therapy

D Ni, D Jiang, HF Valdovinos, EB Ehlerding, B Yu… - Nano …, 2017 - ACS Publications
Although various types of imaging agents have been developed for photoacoustic (PA)
imaging, relatively few imaging agents exhibit high selectivity/sensitivity to the tumor …

An Ionothermal Synthetic Approach to Porous Polyoxometalate‐Based Metal–Organic Frameworks

H Fu, C Qin, Y Lu, ZM Zhang, YG Li, ZM Su, WL Li… - Angewandte …, 2012 - infona.pl
POMs sorgen für Poren: Eine Ionothermalsynthese führte zu porösen offenen Gerüsten auf
Polyoxometallat (POM)‐Basis, deren Strukturen beim Erwärmen bis 300° C unverändert …