Lithium–oxygen batteries and related systems: potential, status, and future

WJ Kwak, Rosy, D Sharon, C Xia, H Kim… - Chemical …, 2020 - ACS Publications
The goal of limiting global warming to 1.5° C requires a drastic reduction in CO2 emissions
across many sectors of the world economy. Batteries are vital to this endeavor, whether used …

Current challenges and routes forward for nonaqueous lithium–air batteries

T Liu, JP Vivek, EW Zhao, J Lei, N Garcia-Araez… - Chemical …, 2020 - ACS Publications
Nonaqueous lithium–air batteries have garnered considerable research interest over the
past decade due to their extremely high theoretical energy densities and potentially low cost …

Why charging Li–air batteries with current low-voltage mediators is slow and singlet oxygen does not explain degradation

S Ahn, C Zor, S Yang, M Lagnoni, D Dewar… - Nature Chemistry, 2023 - nature.com
Although Li–air rechargeable batteries offer higher energy densities than lithium-ion
batteries, the insulating Li2O2 formed during discharge hinders rapid, efficient re-charging …

Redox mediators for high-performance lithium–oxygen batteries

Y Dou, Z Xie, Y Wei, Z Peng, Z Zhou - National Science Review, 2022 - academic.oup.com
Aprotic lithium–oxygen (Li–O2) batteries are receiving intense research interest by virtue of
their ultra-high theoretical specific energy. However, current Li–O2 batteries are suffering …

Threshold potentials for fast kinetics during mediated redox catalysis of insulators in Li–O2 and Li–S batteries

D Cao, X Shen, A Wang, F Yu, Y Wu, S Shi… - Nature Catalysis, 2022 - nature.com
Redox mediators could catalyse otherwise slow and energy-inefficient cycling of Li–S and Li–
O2 batteries by shuttling electrons or holes between the electrode and the solid insulating …

Versatile redox-active organic materials for rechargeable energy storage

G Kwon, Y Ko, Y Kim, K Kim, K Kang - Accounts of Chemical …, 2021 - ACS Publications
Conspectus With the ever-increasing demand on energy storage systems and subsequent
mass production, there is an urgent need for the development of batteries with not only …

Oxygen reduction reactions on single‐or few‐atom discrete active sites for heterogeneous catalysis

T Sharifi, E Gracia‐Espino, A Chen… - Advanced Energy …, 2020 - Wiley Online Library
The oxygen reduction reaction (ORR) is of great importance in energy‐converting processes
such as fuel cells and in metal–air batteries and is vital to facilitate the transition toward a …

Accelerating the reaction kinetics of lithium–oxygen chemistry by modulating electron acceptance–donation interaction in electrocatalysts

C Zhao, J Long, B Zhou, R Zheng, M He, R Li… - Journal of Materials …, 2022 - pubs.rsc.org
Lithium–oxygen batteries (LOBs) have presented great promise in next-generation energy
storage systems due to their high theoretical energy density. However, the sluggish …

Effect of singlet oxygen on redox mediators in lithium–oxygen batteries

HW Lee, JY Kim, JE Kim, YJ Jo, D Dewar… - Journal of Materials …, 2023 - pubs.rsc.org
The use of a redox mediator (RM) to chemically decompose Li2O2 is an efficient approach
to improve the efficiency and cyclability of lithium–oxygen batteries. It has been suggested …

Identifying chemical factors affecting reaction kinetics in Li-air battery via ab initio calculations and machine learning

A Wang, Z Zou, D Wang, Y Liu, Y Li, J Wu… - Energy Storage …, 2021 - Elsevier
Redox mediators are promised to thermodynamically resolve the cathode irreversibility of Li-
air battery. However, the sluggish chemical reaction between mediators and discharge …