Unimolecular reaction systems in which multiple isomers undergo simultaneous reactions
via multiple decomposition reactions and multiple isomerization reactions are of …

Unimolecular isomerization and decomposition reactions of alkylperoxy (RO2),
hydroperoxyalkyl (QOOH), and hydroperoxyalkylperoxy (O2QOOH) radicals play important …

Rate coefficients for alkyl and alkoxy radical decomposition are important in combustion,
biological, and atmospheric processes. In this paper, rate constant expressions for C1 C4 …

We present a new formulation of variational transition state theory (VTST) called multi-
structural VTST (MS-VTST) and the use of this to calculate the rate constant for the 1, 4 …

It has long been known that the product branching ratio between different products in
multichannel reactions is as important as the overall rate of reaction, both in terms of …

The recombination reactions of prototypical alkyl radicals (R) with O2, R+ O2→ RO2, have
been investigated theoretically by using the variational transition state theory and Rice …

Oxidative conversion of lower alkanes over lithium-promoted magnesia catalysts offers a
viable alternative for propene and ethene production. The catalytic performance of propane …

The use of energy transfer data and models in describing nonequilibrium polyatomic
reaction systems is discussed with particular emphasis on the information needed for …

The master equation (ME) provides a powerful technique for modeling reactions that involve
at least one potential energy well. It can be widely applied to reactions with several …

Gaps in the voluminous data on pyrolysis of polyethylene that impede mechanistic
understanding are highlighted, especially for H: C material balances, product distributions at …