A new triazine-based oxidizing reagent, 2-hydroperoxy-4, 6-diphenyl-1, 3, 5-triazine
(Triazox), has been developed. The reagent can be synthesized from inexpensive starting …

A sulfonium ylide participated alkylation and arylation under transition-metal free conditions
is described. The disparate reaction pattern allowed the separate activation of non-ylidic S …

Carbocations, which are positively charged highly electrophilic intermediates, are
efficacious for the direct alkylation of low-reactive nucleophiles. The utilization of …

N, N′-Dimethylated (alkoxy) triazinediones (DMATs-R) with eight different O-alkyl groups
(R), such as benzyl, allyl, and tert-butyl groups, were synthesized in 61–94% yield through …

Novel triazinone-based condensing reagents have been developed. The palladium-
catalyzed O–N allylic rearrangement of 2-(allyloxy)-4, 6-dichloro-1, 3, 5-triazine and …

A new triazine-based cationic leaving group has been developed for the acid-catalyzed
alkylation of O-and C-nucleophiles. There are two synergistic driving forces, namely, stable …

A new triazinone-based reagent for Op-methoxybenzylation has been developed. In spite of
its stability in solid form, this reagent converts a free alcohol into the corresponding p …

Abstract Benzylating reagents, 4-(4, 6-di-t-butyl-1, 3, 5-triazin-2-yl)-4-benzylmorpholinium
triflate, and related derivatives have been developed. The reagents release benzyl triflate as …

A series of (E)-α-silyl-β-alkoxyvinyl-λ3-iodanes was synthesized from iodosylbenzene, BF3–
ether complexes, and terminal ethynylsilanes. The combined use of BF3–OiPr2 and benzyl …

A mild and nonreversible tert-butylation of alcohols and phenols can be achieved in high
yields using the noncoordinating acid–base catalyst [bis (trifluoromethane) sulfonimide and …