1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

This review highlights a number of additives that can be used to make asymmetric reactions
perfect. Without changing other reaction conditions, simply adding additives can lead to …

Enoldiazo esters and amides have proven to be versatile reagents for cycloaddition
reactions that allow highly efficient construction of various carbocycles and heterocycles …

A chiral secondary amine phosphoramide was developed and identified as a powerful
catalyst for the Mukaiyama–Michael addition of fluorinated enol silyl ethers to …

Catalyst-directed access to divergent products involving three different metals that
exclusively form three different products from the same reactants is reported. Each catalyst …

Highly Enantioselective Synthesis of 2,3-Dihydroquinazolinones through Intramolecular
Amidation of Imines | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log …

Gold-catalyzed synthesis of nonsymmetrical heteroaryl-substituted triarylmethanes using 2-
(1-alkynyl)-2-alken-1-ones and vinyldiazo ketones is described. In this catalytic sequence …

Transition-metal catalysts direct 1, 2-C→ C,-O→ C, and-N→ C migrations from β-methylene-
β-silyloxy-β-amido-α-diazoacetates with high selectivity. The key to achieving this unique …

The first synthesis of novel fused pyridazines has been realized starting from 1, 3-diketones
involving a Diaza–Wittig reaction as a key step. A convenient strategy was elaborated to …

Diazo compounds represent a type of very important synthetic intermediates, which
demonstrate wide applications in organic synthesis, continuous-in-flow technology, polymer …