In this review, transition metal-catalyzed methodologies and applications that exploit C–C
bond cleavage of vinylcyclopropanes (VCPs) are summarized with a focus on cycloaddition …

N-Tosylhydrazones have recently emerged as useful synthons in a variety of transition-metal-
catalyzed and transition-metal-free reactions, which affords novel methodologies for the …

Covering: 2000–2018 In this review, we highlight recent examples of natural product total
syntheses employing transition metal-mediated/catalyzed carbonylative cyclization …

Since the time of Giacomo Ciamician at the beginning of the 20th century, photochemical
transformations have been recognized as contributing to sustainable chemistry. Electronic …

The pyrazole is a very important heterocycle in pharmaceutical and agrochemical
industries.[1] Compounds containing the pyrazole substructure find application in a wide …

This review is focused on the recent developments in transition‐metal‐free transformations
using N‐tosylhydrazones, emerging building blocks in contemporary organic chemistry …

A diazo species is trapped in an intermolecular fashion by two independent ion species in
tandem at the carbene center to install an electrophile and a nucleophile on the same …

The partners decide: The C C bond‐forming reductive cross‐coupling of alkenylboronic
acids and tosylhydrazones takes place under mild reaction conditions without the need of a …

A catalytic synthetic route to highly functionalized chiral cyclopropane derivatives was
developed by Michael-initiated cyclopropanation of α-substituted acroleins with aryl-and …

The cyclopropane ring is present in a large number of bioactive molecules as its
incorporation often greatly alters their physiochemical properties. The synthesis of such motif …