Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Slow magnetization dynamics in a series of two-coordinate iron (II) complexes

JM Zadrozny, M Atanasov, AM Bryan, CY Lin… - Chemical …, 2013 - pubs.rsc.org
A series of two-coordinate complexes of iron (II) were prepared and studied for single-
molecule magnet behavior. Five of the compounds, Fe [N (SiMe3)(Dipp)] 2 (1), Fe [C …

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Photomagnetism in cyano-bridged bimetal assemblies

S Ohkoshi, H Tokoro - Accounts of chemical research, 2012 - ACS Publications
The study of photoinduced phase-transition materials has implications for the fields of
inorganic chemistry, solid-state chemistry, and materials science. Cyano-bridged bimetal …

Molecularly designed architectures–the metalloligand way

G Kumar, R Gupta - Chemical Society Reviews, 2013 - pubs.rsc.org
Designed materials offer noteworthy applications which are often architecture dependent.
Despite knowing such a fact, one of the major challenges faced by the scientific community …

Controlled intramolecular electron transfers in cyanide-bridged molecular squares by chemical modifications and external stimuli

M Nihei, Y Sekine, N Suganami… - Journal of the …, 2011 - ACS Publications
A series of cyanide bridged Fe− Co molecular squares,[Co2Fe2 (CN) 6 (tp*) 2 (dtbbpy)
4](PF6) 2· 2MeOH (1),[Co2Fe2 (CN) 6 (tp*) 2 (bpy) 4](PF6) 2· 2MeOH (2), and [Co2Fe2 (CN) …