[HTML][HTML] The shape of porphyrins

CJ Kingsbury, MO Senge - Coordination Chemistry Reviews, 2021 - Elsevier
Porphyrin molecules are a widely exploited biochemical moiety, with uses in medicinal
chemistry, sensing and materials science. The shape of porphyrins, as an aromatic unit, is …

Emerging applications of porphyrins and metalloporphyrins in biomedicine and diagnostic magnetic resonance imaging

M Imran, M Ramzan, AK Qureshi, MA Khan, M Tariq - Biosensors, 2018 - mdpi.com
In recent years, scientific advancements have constantly increased at a significant rate in the
field of biomedical science. Keeping this in view, the application of porphyrins and …

[图书][B] The Jahn-Teller effect and vibronic interactions in modern chemistry

I Bersuker - 2013 - books.google.com
The first half of the title of this book may delude the uninitiated reader. The term'" Jahn-Teller
effect," taken literally, refers to a special effect inherent in particular molecular systems …

[图书][B] Cytochromes c: evolutionary, structural and physicochemical aspects

GR Moore, GW Pettigrew - 2012 - books.google.com
Cytochromes c are haemoproteins which carry out electron transfer in a wide variety of
biological systems, necessitating different kinds of cytochrome c to fulfill different biological …

Conformational control of cofactors in nature–the influence of protein-induced macrocycle distortion on the biological function of tetrapyrroles

MO Senge, SA MacGowan, JM O'Brien - Chemical Communications, 2015 - pubs.rsc.org
Tetrapyrrole-containing proteins are one of the most fundamental classes of enzymes in
nature and it remains an open question to give a chemical rationale for the multitude of …

Spin-state/stereochemical relationships in iron porphyrins: implications for the hemoproteins

WR Scheidt, CA Reed - Chemical Reviews, 1981 - ACS Publications
An axiom of hemoprotein biochemistry is that mo-lecular structure provides the basis for an
understand-ing of how these proteins work. Chemical curiosity is aroused by the …

Recent advances in the stereochemistry of metallotetrapyrroles

WR Scheidt, YJ Lee - Metal complexes with tetrapyrrole ligands I, 2005 - Springer
Abstract Information pertaining to the stereochemistry of metalloporphyrins and other
tetrapyrroles continues to expand. The present article reviews important developments of …

Metalloporphyrin nanoparticles: Coordinating diverse theranostic functions

S Shao, V Rajendiran, JF Lovell - Coordination chemistry reviews, 2019 - Elsevier
Metalloporphyrins serve key roles in natural biological processes and also have
demonstrated utility for biomedical applications. They can be encapsulated or grafted in …

Myoglobin discriminates between O2, NO, and CO by electrostatic interactions with the bound ligand

JS Olson, GN Phillips Jr - JBIC Journal of Biological Inorganic Chemistry, 1997 - Springer
Most biological substrates have distinctive sizes, shapes, and charge distributions which can
be recognized specifically by proteins. In contrast, myoglobin must discriminate between the …

The missing heme spin state and a model for cytochrome c'. The mixed S= 3/2, 5/2 intermediate spin ferric porphyrin: perchlorato (meso-tetraphenylporphinato) iron (III …

CA Reed, T Mashiko, SP Bentley… - Journal of the …, 1979 - ACS Publications
The uncommon d5 intermediate spin state is found in a series of mfjo-
tetraphenylporphyrinatoiron (lll) complexes of general formulaFe (Y)(TPP) where Y is a so …