This review presents the results of a detailed analysis of the role of isochoric heat capacity
as a key thermodynamic property of matter in the investigation of critical and supercritical …

We establish via an in-depth analysis of experimental data that the dimensionless
compressibility (proportional to the dimensionless amplitude of long wavelength thermal …

By definition, the distinction between a gas and a liquid ceases to exist beyond the critical
point for pure fluids. Nevertheless, there remains a strong desire to attribute gas-like or liquid …

We briefly overview the theoretical advances for the fundamental description on the
supercritical fluids since the late 1980s. The concept of supercritical gas-liquid boundary …

This work proposes a classification algorithm based on the radical Voronoi tessellation to
define the Widom delta, supercritical gas-liquid coexistence region, of polyatomic molecules …

Quantifying the role of solvation in soft matter and complex solutions has been made
challenging by the fluctuational nature of solvation, as well as by the tedious calculus …

We propose in this paper a theoretical model for fluid state thermodynamics based on
modeling the fluctuation distributions and, hence, the corresponding moment generating …

Abstract The Kirkwood-Buff integrals (KBIs) provide a link between structuring on an atomic
scale accessed by simulations and thermodynamics, which makes it a powerful tool for …

В обзоре приведены результаты подробного анализа роли изохорной теплоемкости,
как ключевого термодинамического свойства вещества, в исследовании критических и …

The particle number, energy, and volume probability distributions in the canonical,
isothermal-isobaric, grand canonical, and isobaric-isenthalpic ensembles are investigated …