Ultracold molecules and ultracold chemistry

MT Bell, T P. Softley - Molecular Physics, 2009 - Taylor & Francis
The recent development of a range of new methods for producing samples of gas-phase
molecules that are translationally cold (K) or ultracold (mK) is driving efforts to study reactive …

Reactions at very low temperatures: gas kinetics at a new frontier

IWM Smith - Angewandte Chemie International Edition, 2006 - Wiley Online Library
A new era in chemical kinetics was heralded 20 years ago by the results reported by
Bertrand Rowe, then at the Laboratoire d AØrothermique in Meudon.[1] Using an apparatus …

The UMIST database for astrochemistry 1995

TJ Millar, PRA Farquhar, K Willacy - Astronomy and Astrophysics …, 1997 - aas.aanda.org
We report the release of a new version of the UMIST database for astrochemistry. The
database contains the rate coefficients of 3864 gas-phase reactions important in interstellar …

Chemical evolution in preprotostellar and protostellar cores

EA Bergin, WD Langer - The Astrophysical Journal, 1997 - iopscience.iop.org
The chemistry of developing and collapsing low-mass protostellar cores is followed using a
chemical code with a time-varying density. Two evolutionary scenarios are represented …

Rate constants for the reactions of CN with hydrocarbons at low and ultra-low temperatures

IR Sims, JL Queffelec, D Travers, BR Rowe… - Chemical Physics …, 1993 - Elsevier
The pulsed laser-photolysis (PLP), time-resolved laser-induced fluorescence (LIF) technique
has been used to study the reactions of the CN radical with CH 4, C 2 H 6, C 2 H 4, C 3 H 6 …

A study of the physics and chemistry of TMC-1

P Pratap, JE Dickens, RL Snell… - The Astrophysical …, 1997 - iopscience.iop.org
We present a comprehensive study of the physical and chemical conditions along the TMC-
1 ridge. Temperatures were estimated from observations of CH 3 CCH, NH 3, and CO …

Near-threshold inelastic collisions using molecular beams with a tunable velocity

JJ Gilijamse, S Hoekstra, SYT van de Meerakker… - Science, 2006 - science.org
Molecular scattering behavior has generally proven difficult to study at low collision
energies. We formed a molecular beam of OH radicals with a narrow velocity distribution …

The UMIST database for astrochemistry 2022

TJ Millar, C Walsh, M Van de Sande… - Astronomy & …, 2024 - aanda.org
Context. Detailed astrochemical models are a key component to interpret the observations of
interstellar and circumstellar molecules since they allow important physical properties of the …

Ultralow temperature kinetics of neutral–neutral reactions. The technique and results for the reactions CN+O2 down to 13 K and CN+NH3 down to 25 K

IR Sims, JL Queffelec, A Defrance… - The Journal of …, 1994 - pubs.aip.org
An entirely new experimental method is described which enables the rate constants of
neutral–neutral gas‐phase reactions to be measured at ultralow temperatures. The …

Neutral–neutral reactions at the temperatures of interstellar clouds Rate coefficients for reactions of C 2 H radicals with O 2, C 2 H 2, C 2 H 4 and C 3 H 6 down to 15 K

D Chastaing, PL James, IR Sims, IWM Smith - Faraday Discussions, 1998 - pubs.rsc.org
A CRESU (Cine′ tique de Re′ action en Ecoulement Supersonique Uniforme) apparatus
has been used to measure rate constants for the reactions of the ethynyl radical (C2H) with …