This Article revisits the “Definition of the Halogen Bond (IUPAC Recommendations
2013)”[Desiraju, GR Pure Appl. Chem. 2013, 85 (8), 1711–1713], recommendations that fail …

The unexpectedly facile insertion of Rh or Ir into a B–Ph bond (reversible for Rh) converts a
borane/bis (phosphine) precursor into a boryl/bis (phosphine) PBP pincer ligand …

This review aims to provide a comprehensive overview of the emerging field of redox-active
pincer ligands. As such, following a short general introduction on ligand-centred redox …

Following the report on the successful use of SiNN pincer complexes of iridium as catalysts
for dehydrogenative borylation of terminal alkynes (DHBTA) to alkynylboronates, this work …

The use of XCX‐aryl pincer metal complexes as catalysts started immediately after their
discovery in 1976. Nowadays pincer metal complexes are commonly used as a new …

CO2 catalytic hydrogenation to formate was achieved (TONmax= ca. 3800) in the presence
of the neutral, halide‐free, coordinatively saturated tris (carbonyl) manganese pincer‐type …

Herein we report the synthesis and spectroscopic observation of a Pt complex featuring a
P2Si ligand containing a central silylene donor connected to phosphines via two o-arylene …

The synthesis, structural characterization and photophysical properties of a series of
platinum (II) complexes of benzannulated pincer-type diarylamido ligands are described …

Proligands based on bis (8-quinolinyl) amine (L1) were prepared containing one (L2) and
two (L3) benzo-fused N-heterocyclic phenanthridinyl (3, 4-benzoquinolinyl) units. Taken as …

A set of diarylamido-based unsymmetrical [PNNox] pincer ligands containing a chiral
oxazoline ring have been synthesized and their nickel and palladium complexes [(2-PPh2 …