The syn‐dihydroxylation of olefinic group is one of the most important synthetic
transformations which leads to the controlled formation of syn‐diol. Such 1, 2‐diol structure …

Herein, we reported a facile and scalable approach for the synthesis of Fe-based MOF MIL-
88A (Fe) via a simple liquid-phase route at atmosphere pressure, and its application as a …

A homogeneous Mo (VI)-dioxo complex including tetradentate bis (phenol) diamine ligand
covalently grafted onto amine-functionalized heterogeneous magnetic nanoparticles has …

Selective oxidation of olefins to desired products such as epoxides is highly demanded in
chemical industry. It remains challenging to achieve high selectivity for production of …

Selective oxidation of various alkanes/alkyl aromatics to corresponding carbonyl
compounds has been carried out with very high conversion (∼ 98%) and selectivity (up to …

Polyoxometalate-based heterogeneous materials were prepared by the immobilization of 12-
phosphomolybdic acid (PMA) on periodic mesoporous organosilicas containing embedded …

The assignment of peroxo stretching frequencies for Molybdenum and Tungsten complexes
is studied by DFT and MP2 calculations. We found that M06 functional is unsuitable for …

A comparative gas-phase density functional theory (DFT) study of the catalytic epoxidation of
olefins with the possible intermediates [CpMo VI (CF 3)(O) 2] and CpMo VI (CF 3)(OO)(O) is …

Several molybdenum (VI) dioxo complexes have been investigated as catalyst precursors
for allylic alcohol epoxidation using mainly hydrogen peroxide as oxidant. All catalysts …

NMR study of the oxidation of several Mo (II) precatalysts [CpMo (CO) 3 R](R= CH 2 COOC 2
H 5 1, CH 2 COOBornyl 5, CH 3 6, CH 2 C 6 H 5 7, CH 2 C 6 F 5 8) with tert …