Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: from molecular design to functional …

Y Zhang, R Torres-Cavanillas, X Yan, Y Zeng… - Chemical Society …, 2024 - pubs.rsc.org
During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

Enlightening the alkali ion role in the photomagnetic effect of FeCo Prussian blue analogues

J Glatz, JR Jiménez, L Godeffroy… - Journal of the …, 2022 - ACS Publications
FeCo Prussian blue analogues of general formula A x Co y [Fe (CN) 6] z are responsive,
non-stoichiometric materials whose magnetic and optical properties can be reversibly …

Stimuli-responsive magnetic materials: impact of spin and electronic modulation

K Kaushik, S Mehta, M Das, S Ghosh… - Chemical …, 2023 - pubs.rsc.org
Addressing molecular bistability as a function of external stimuli, especially in spin-crossover
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …

Two-Step Thermoinduced Metal-to-Metal Electron Transfer and ON/OFF Photoswitching in a Molecular [Fe2Co2] Square Complex

S Kamilya, S Ghosh, Y Li, P Dechambenoit… - Inorganic …, 2020 - ACS Publications
A cyanide-bridged [Fe2Co2] molecular square complex,{[Fe (Tp)(CN) 3] 2 [Co (L) 2] 2}(BF4)
2· 2CH3CN· 6H2O [1; Tp= hydrotris (pyrazol-1-yl) borate and L= bis (1-ethyl-1 H-imidazol-2 …

Spin-state switching: chemical modulation and the impact of intermolecular interactions in manganese (iii) complexes

S Bagchi, S Kamilya, S Mehta, S Mandal… - Dalton …, 2023 - pubs.rsc.org
A series of mononuclear manganese (III) complexes [Mn (X-sal2-323)](ReO4)(X= 5 Cl, 1; X=
5 Br, 2; X= 3, 5 Cl, 3; X= 3, 5 Br, 4; and X= 5 NO2, 5), containing hexadentate ligands …

Modulation of Charge Distribution in Cobalt-α-Diimine Complexes toward Valence Tautomerism

MA Hay, JT Janetzki, VJ Kumar, RW Gable… - Inorganic …, 2022 - ACS Publications
Valence tautomerism (VT) and spin crossover (SCO) are promising avenues for developing
a range of molecular materials for sensing, memory, and optoelectronic applications …

Impact of Counteranion on Reversible Spin-State Switching in a Series of Cobalt (II) Complexes Containing a Redox-Active Ethylenedioxythiophene-Based …

S Ghosh, S Ghosh, S Kamilya, S Mandal… - Inorganic …, 2022 - ACS Publications
The self-assembly of a redox-active ethylenedioxythiophene (EDOT)-terpyridine-based
tridentate ligand and cobalt (II) unit with different counteranions has led to a series of new …

Photo‐thermal switching of individual plasmonically activated spin crossover nanoparticle imaged by ultrafast transmission electron microscopy

Y Hu, M Picher, NM Tran, M Palluel… - Advanced …, 2021 - Wiley Online Library
Spin crossover (SCO) is a promising switching phenomenon when implemented in
electronic devices as molecules, thin films or nanoparticles. Among the properties …

Integration of privacy protection and blockchain-based food safety traceability: Potential and challenges

M Lei, L Xu, T Liu, S Liu, C Sun - Foods, 2022 - mdpi.com
Concern about food safety has become a hot topic, and numerous researchers have come
up with various effective solutions. To ensure the safety of food and avoid financial loss, it is …